Revolutionizing dye adsorption: amino functionalized Zeolitic Imidazole Framework-8 for effective methyl blue removal
摘要
The discharge of untreated wastewater containing synthetic dyes from the industry significantly pollutes water sources. Metal–Organic Frameworks especially Zeolitic Imidazolate Framework-8 have emerged as promising materials in dye wastewater treatment, offering innovative potential for mitigating this pollution. In this research study, the amino-functionalized Zeolitic Imidazole Framework-8 was synthesized and characterized using Field-Emission Scanning Electron Microscopy, Energy Dispersive X-ray Spectroscopy, Fourier Transform Infrared Spectroscopy, X-ray Diffraction, X-ray Photoelectron Spectroscopy and Brunauer–Emmett–Teller. The suitability of amino-functionalized Zeolitic Imidazole Framework-8 for dye removal was determined via a batch adsorption study, and the effects of several adsorption factors were investigated, including the initial concentration of methyl blue (40–200 ppm) the effect of pH condition (pH 3–11), and reaction time (30–180 min). Several kinetic isotherm models, including Langmuir, Freundlich, Pseudo First Order, and Pseudo Second Order, were applied to ascertain the adsorption mechanism. From the results obtained, the adsorption capacity of amino-functionalized Zeolitic Imidazole Framework-8 recorded is 537.4 mg/g. The adsorption isotherm is well-suited to the Freundlich model (R2 = 0.9453) and the kinetic of adsorption is most fitted with Pseudo-second order (R2 = 0.9999). Thus, these results suggest that amino-functionalized Zeolitic Imidazole Framework-8 is a highly efficient adsorbent for methyl blue, operating predominantly through multilayer adsorption and chemisorption. For future research, it is recommended to study the selectivity of amino-functionalized Zeolitic Imidazole Framework-8 for various dyes and contaminants, as well as to evaluate its performance in real wastewater samples to assess its practical applicability in complex matrices.
Graphical Abstract