Linear and non-linear rheology of high molecular weight polyethylene filled withFe2O3-treated graphene nanofiller
摘要
This paper aims at studying linear and non-linear rheology of neat high molecular weight polyethylene (HMWPE) and HMWPE filled with 2wt% magnetic graphene oxide nanofiller (GnPmFe2O3). GnPmFe2O3 was synthesized and characterized using FTIR analysis. The presence of Fe–O bonds and α-Fe2O3 (hematite) on the surface of GnPs was verified by distinct peaks. Nanocomposites of HMWPE/GnPmFe2O3 were prepared through melt mixing of 0, 1, 2, and 4wt% of GnPmFe2O3 nanoparticles and HMWPE. The prepared nanocomposites were sheeted at 200°C using a hot press in a magnetic field resulting in aligning the GnPmFe2O3 in HMWPE. The linear rheology indicated solid-like moduli at low frequencies with no terminal zone for HMWPE and 2wt% HMWPE/GnPmFe2O3and lower moduli for HMWPE/GnPmFe2O3. The complex viscosity displayed similar shear thinning trend, however, the consistency indexes were quite different with a higher value for HMWPE. Both samples showed a wide range of relaxation times. Most of the molecules relaxed within 100s after removing the shear, however, a part of molecules needed longer times. The start-up experiments at various shear rates indicated further viscous behavior at low shear rates and more elastic one at high shear rates for both samples. The height of stress overshoots for HMWPE/GnPmFe2O3 was pretty lower than that of HMWPE. Applying a constant shear rate followed by the flow cessation and various rest times resulted in decreasing the height of stress overshoots with rest time for both samples. The results of flow reversal experiment after various rest times indicated higher stress overshoot for shorter times for both materials.
Graphical Abstract