<p>Maximum antimicrobial efficiency of silver nanoparticles (Ag NPs) are obtained when it is well distributed over a template. In this study, Ag NPs are decorated over graphitic carbon nitride (g-C<sub>3</sub>N<sub>4</sub>) nanosheets by reducing silver precursor using ascorbic acid with room temperature sonication process. Size and decoration of the Ag NPs is controlled by varying the concentration of silver precursor. Presence of crystalline Ag NPs were confirmed by powder X-ray diffraction patterns and 2D nanosheet structure of g-C<sub>3</sub>N<sub>4</sub> with silver decoration is visualized through scanning electron microscopy and transmission electron microscopy techniques. The band gap of pristine g-C<sub>3</sub>N<sub>4</sub> is narrowed by Ag loading and causing a red shift in absorption edge of pristine g-C<sub>3</sub>N<sub>4</sub>. Heptazine heterostructure of g-C<sub>3</sub>N<sub>4</sub> made up of C-N and C = N bands are confirmed through Fourier transform infrared spectroscopy. Bactericidal effect of the synthesized g-C<sub>3</sub>N<sub>4</sub> nanosheets, Ag NPs, and Ag/g-C<sub>3</sub>N<sub>4</sub> were examined using agar well diffusion method on the pathogens namely Staphylococcus aureus (<i>S. aureus</i>) a gram positive bacteria and Escherichia coli (<i>E. coli</i>) a gram negative bacteria. The g-C<sub>3</sub>N<sub>4</sub> nanosheets are suitable 2D material to act as a template for Ag NPs decoration. This helps us in realizing the true potential of the Ag NPs as an antibacterial agent. The sample with maximum concentration of Ag NPs have 87.5% and 88.2% zone of inhibition as antibacterial efficiency of standard against <i>E. coli</i> and <i>S. aureus</i>, respectively.</p>

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Silver Nanoparticles Decorated Exfoliated Graphitic Carbon Nitride for Antimicrobial Application

  • Selvan Kandasamy,
  • Deepak Raju,
  • Manivannan Sellaperumal,
  • Shobin Loukkose Rosemary

摘要

Maximum antimicrobial efficiency of silver nanoparticles (Ag NPs) are obtained when it is well distributed over a template. In this study, Ag NPs are decorated over graphitic carbon nitride (g-C3N4) nanosheets by reducing silver precursor using ascorbic acid with room temperature sonication process. Size and decoration of the Ag NPs is controlled by varying the concentration of silver precursor. Presence of crystalline Ag NPs were confirmed by powder X-ray diffraction patterns and 2D nanosheet structure of g-C3N4 with silver decoration is visualized through scanning electron microscopy and transmission electron microscopy techniques. The band gap of pristine g-C3N4 is narrowed by Ag loading and causing a red shift in absorption edge of pristine g-C3N4. Heptazine heterostructure of g-C3N4 made up of C-N and C = N bands are confirmed through Fourier transform infrared spectroscopy. Bactericidal effect of the synthesized g-C3N4 nanosheets, Ag NPs, and Ag/g-C3N4 were examined using agar well diffusion method on the pathogens namely Staphylococcus aureus (S. aureus) a gram positive bacteria and Escherichia coli (E. coli) a gram negative bacteria. The g-C3N4 nanosheets are suitable 2D material to act as a template for Ag NPs decoration. This helps us in realizing the true potential of the Ag NPs as an antibacterial agent. The sample with maximum concentration of Ag NPs have 87.5% and 88.2% zone of inhibition as antibacterial efficiency of standard against E. coli and S. aureus, respectively.