<p>This study investigates the physical, magnetic, dielectric, and switching field distribution behavior of chemically synthesized N<sub>0.5</sub>Mg<sub>0.5</sub>Fe<sub>2−y</sub>Pr<sub>y</sub>O<sub>4</sub> (<InlineEquation ID="IEq1"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="12648_2025_3661_Article_IEq1.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="165" /> </InlineMediaObject> <EquationSource Format="TEX">\(\text{y}=0.0, 0.1, 0.2, 0.3, 0.4\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mtext>y</mtext> <mo>=</mo> <mn>0.0</mn> <mo>,</mo> <mn>0.1</mn> <mo>,</mo> <mn>0.2</mn> <mo>,</mo> <mn>0.3</mn> <mo>,</mo> <mn>0.4</mn> </mrow> </math></EquationSource> </InlineEquation>) spinel ferrites (SFs) by self-ignition route. The structural analysis reveals a range of lattice constants influenced by Pr<sup>3+</sup> substitution, which also impacts crystallite size and densification. Tetrahedral and octahedral absorption bands associated with metal–oxygen bonds, metal–oxygen-metal bonds, and lattice vibrations were identified using FTIR spectra. The presence of five Raman peaks corresponding to pure Ni–Mg and Pr<sup>3+</sup> doped Ni–Mg SFs vibration modes were identified in Raman spectra. The particle size was reduced with the addition of Pr<sup>3+</sup> ions in Ni–Mg SFs. Magnetic measurements indicate a decrease in saturation magnetization (M<sub>S</sub>) and an increase in coercivity (H<sub>C</sub>) with doping of Pr<sup>3+</sup> content. The tangent loss, dielectric constant, and loss of Pr<sup>3+</sup> doped Ni–Mg SFs change with changing frequency and Pr<sup>3+</sup> doping. The magnetic, and dielectric properties exhibit significant changes, highlighting the potential for tunable magnetic, and dielectric response under different concentrations of Pr<sup>3+</sup>. The switching field distribution analysis shows a variation in magnetic reversal processes, correlated with the Pr<sup>3+</sup> concentration. These findings suggest that Pr<sup>3+</sup> doped Ni–Mg SFs are favorable candidates for high-frequency applications.</p>

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Physical, magneto-dielectric, and switching field distribution analysis of chemically obtained Ni0.5Mg0.5Fe2−yPryO4 spinel ferrites

  • Abdullah Saad Alsubaie,
  • Raza Ali,
  • Mohamed Mohamed Soliman,
  • Salah M. El-Bahy,
  • Mohamed H. Helal,
  • A. U. Rahman

摘要

This study investigates the physical, magnetic, dielectric, and switching field distribution behavior of chemically synthesized N0.5Mg0.5Fe2−yPryO4 ( \(\text{y}=0.0, 0.1, 0.2, 0.3, 0.4\) y = 0.0 , 0.1 , 0.2 , 0.3 , 0.4 ) spinel ferrites (SFs) by self-ignition route. The structural analysis reveals a range of lattice constants influenced by Pr3+ substitution, which also impacts crystallite size and densification. Tetrahedral and octahedral absorption bands associated with metal–oxygen bonds, metal–oxygen-metal bonds, and lattice vibrations were identified using FTIR spectra. The presence of five Raman peaks corresponding to pure Ni–Mg and Pr3+ doped Ni–Mg SFs vibration modes were identified in Raman spectra. The particle size was reduced with the addition of Pr3+ ions in Ni–Mg SFs. Magnetic measurements indicate a decrease in saturation magnetization (MS) and an increase in coercivity (HC) with doping of Pr3+ content. The tangent loss, dielectric constant, and loss of Pr3+ doped Ni–Mg SFs change with changing frequency and Pr3+ doping. The magnetic, and dielectric properties exhibit significant changes, highlighting the potential for tunable magnetic, and dielectric response under different concentrations of Pr3+. The switching field distribution analysis shows a variation in magnetic reversal processes, correlated with the Pr3+ concentration. These findings suggest that Pr3+ doped Ni–Mg SFs are favorable candidates for high-frequency applications.