<p>To investigate the influence of CO<sub>2</sub> on the co-pyrolysis characteristics of sewage sludge and poplar sawdust, a 1:1 (w/w) blend of sewage sludge and poplar sawdust was employed as the experimental material. Pyrolysis experiments were performed in a fixed-bed reactor under both CO<sub>2</sub> and N<sub>2</sub> atmospheres across a temperature range of 500–800 ℃. The influence of CO<sub>2</sub> atmosphere on the composition of pyrolysis gas and tar was examined. The results show that increasing temperature decreases the char yield, while increasing the yields of CO, CH<sub>4</sub>, and H<sub>2</sub>. In comparison to N<sub>2</sub>, a CO<sub>2</sub> atmosphere promotes the generation of CH<sub>4</sub> and CO, while suppressing the formation of H<sub>2</sub>. CO<sub>2</sub> atmosphere influence on the composition of tar. The maximum tar yield and the highest total peak area corresponding to phenolic compounds were observed at 500 ℃ under CO<sub>2</sub>, whereas these values were recorded at 600 ℃ under N<sub>2</sub>. Increasing the temperature within CO<sub>2</sub> facilitates the formation of aromatic hydrocarbons in tar. The content of oxygen-containing compounds exhibits an initial decline followed by a subsequent increase.</p>

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The Influence of CO2 on Co-Pyrolysis Characteristics of Sewage Sludge and Poplar Sawdust

  • Chen Feng,
  • Xuda Li,
  • Jiaying Xiang,
  • Dongpo Shi,
  • Jiaoyu Zhang,
  • Shenghua Zhu

摘要

To investigate the influence of CO2 on the co-pyrolysis characteristics of sewage sludge and poplar sawdust, a 1:1 (w/w) blend of sewage sludge and poplar sawdust was employed as the experimental material. Pyrolysis experiments were performed in a fixed-bed reactor under both CO2 and N2 atmospheres across a temperature range of 500–800 ℃. The influence of CO2 atmosphere on the composition of pyrolysis gas and tar was examined. The results show that increasing temperature decreases the char yield, while increasing the yields of CO, CH4, and H2. In comparison to N2, a CO2 atmosphere promotes the generation of CH4 and CO, while suppressing the formation of H2. CO2 atmosphere influence on the composition of tar. The maximum tar yield and the highest total peak area corresponding to phenolic compounds were observed at 500 ℃ under CO2, whereas these values were recorded at 600 ℃ under N2. Increasing the temperature within CO2 facilitates the formation of aromatic hydrocarbons in tar. The content of oxygen-containing compounds exhibits an initial decline followed by a subsequent increase.