<p>Titanium silicon carbide (Ti<sub>3</sub>SiC<sub>2</sub>) is one of the significant phases in the MAX (M<sub><i>n</i>+1</sub>AX<sub><i>n</i></sub>) system. Its high thermal conductivity, low hardness, and excellent resistance to thermal shock, corrosion, and oxidation make it a popular reinforcement material for novel ceramic composite designs. On the other hand, 12 mol% ceria-stabilized tetragonal zirconia polycrystals (12Ce-TZP) are known for their extremely high fracture toughness due to martensite-like phase transformations; however, they exhibit low thermal conductivity. Therefore, the scope of the current research is to investigate 12Ce-TZP/Ti<sub>3</sub>SiC<sub>2</sub> MAX composites, which can potentially be used as new cutting tool materials and to achieve easy machinability through computer numerical control (CNC)-based drilling operations. Here, the thermal conductivity behavior, CNC machinability, and microstructural characteristics of the as-received 12Ce-TZP and 12Ce-TZP/<i>x</i>Ti<sub>3</sub>SiC<sub>2</sub> MAX; <i>x</i> = 0.5 and 2.5 wt.% composites sintered at 1550°C for 2 h were investigated. Based on the overall results, the thermal conductivity values of 12Ce-TZP/2.5 wt.% Ti<sub>3</sub>SiC<sub>2</sub> MAX composites were calculated to be 1.54±0.04 W/mˑK at 1000°C and 2.17±0.03 W/mˑK at ambient temperature. These newly designed composites, incorporating Ti<sub>3</sub>SiC<sub>2</sub> at 0.5 and 2.5 wt.% in the 12Ce-TZP matrix, were successfully drilled into circular holes using CNC. Considering the detailed results of scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX), the formation of interlocking and intergranular network structures between 12Ce-TZP grains and the Ti<sub>3</sub>SiC<sub>2</sub> phase plays a key role in achieving good machinability characteristics for the newly designed 12Ce-TZP/2.5 wt.% Ti<sub>3</sub>SiC<sub>2</sub> MAX composites. We expect that the results presented here will open a new door for converting non-machinable ceramics to a machinable form.</p>

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Microstructural, thermal, and machinability properties of ceria-stabilized tetragonal zirconia polycrystalline/titanium silicon carbide (Ce-TZP/Ti3SiC2 MAX) composites for cutting tool applications

  • Arife Yurdakul,
  • Orkun Tunçkan

摘要

Titanium silicon carbide (Ti3SiC2) is one of the significant phases in the MAX (Mn+1AXn) system. Its high thermal conductivity, low hardness, and excellent resistance to thermal shock, corrosion, and oxidation make it a popular reinforcement material for novel ceramic composite designs. On the other hand, 12 mol% ceria-stabilized tetragonal zirconia polycrystals (12Ce-TZP) are known for their extremely high fracture toughness due to martensite-like phase transformations; however, they exhibit low thermal conductivity. Therefore, the scope of the current research is to investigate 12Ce-TZP/Ti3SiC2 MAX composites, which can potentially be used as new cutting tool materials and to achieve easy machinability through computer numerical control (CNC)-based drilling operations. Here, the thermal conductivity behavior, CNC machinability, and microstructural characteristics of the as-received 12Ce-TZP and 12Ce-TZP/xTi3SiC2 MAX; x = 0.5 and 2.5 wt.% composites sintered at 1550°C for 2 h were investigated. Based on the overall results, the thermal conductivity values of 12Ce-TZP/2.5 wt.% Ti3SiC2 MAX composites were calculated to be 1.54±0.04 W/mˑK at 1000°C and 2.17±0.03 W/mˑK at ambient temperature. These newly designed composites, incorporating Ti3SiC2 at 0.5 and 2.5 wt.% in the 12Ce-TZP matrix, were successfully drilled into circular holes using CNC. Considering the detailed results of scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX), the formation of interlocking and intergranular network structures between 12Ce-TZP grains and the Ti3SiC2 phase plays a key role in achieving good machinability characteristics for the newly designed 12Ce-TZP/2.5 wt.% Ti3SiC2 MAX composites. We expect that the results presented here will open a new door for converting non-machinable ceramics to a machinable form.