Quantum dynamical studies on a model for reactions exhibiting post-transition state bifurcation
摘要
Classical and quantum dynamical studies are undertaken on a model for post-transition state bifurcation (PTSB) reactions exhibiting a valley ridge inflection (VRI) point on the potential energy surface. We seek the quantum manifestations of the dynamical influence of VRIs highlighted in the recent work by García-Garrido and Wiggins.