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<p>Sodium-ion batteries are treated as a drop-in technology to complement lithium-ion batteries in applications such as entry-level cars and stationary storage. This study compares water-based processing of the sodium-ion battery active material sodium vanadium phosphate (NVP/C) with processing using slurries based on the organic solvent NMP. By utilizing CMC/SBR as a binder, the adhesion strength, flexibility, electrical resistance, and rate capability were improved. These superior properties could be maintained at increasing the drying rate by a factor of 8. However, electrodes processed with the water-based binder system also suffered from binder migration at higher drying rates. To enable high-throughput processing, a strategy involving simultaneous multilayer coating of a primer and electrode slurry was explored. This approach helped mitigate the negative effects of binder migration.</p>

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Water-based vs. organic solvent-based processing of NVP/C cathodes for sodium-ion batteries toward higher processing rates

  • 期刊论文

  • 出版模式：

    开放获取

  • 发表日期：

    2026年3月20日

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  • David Burger,
  • Hanqing Sun,
  • Xuebin Wu,
  • Noah Keim,
  • Marcus Müller,
  • Werner Bauer,
  • Helmut Ehrenberg,
  • Philip Scharfer,
  • Wilhelm Schabel

摘要

Sodium-ion batteries are treated as a drop-in technology to complement lithium-ion batteries in applications such as entry-level cars and stationary storage. This study compares water-based processing of the sodium-ion battery active material sodium vanadium phosphate (NVP/C) with processing using slurries based on the organic solvent NMP. By utilizing CMC/SBR as a binder, the adhesion strength, flexibility, electrical resistance, and rate capability were improved. These superior properties could be maintained at increasing the drying rate by a factor of 8. However, electrodes processed with the water-based binder system also suffered from binder migration at higher drying rates. To enable high-throughput processing, a strategy involving simultaneous multilayer coating of a primer and electrode slurry was explored. This approach helped mitigate the negative effects of binder migration.