<p>A multiphase Eulerian two-fluid model was developed to simulate the reduction of FeO on a graphite surface immersed in a CaO-SiO<sub>2</sub>-FeO smelting slag. Three phases are considered: the primary slag melt, containing FeO as the sole reactive species; CO gas bubbles generated by the reduction reaction; and iron particles formed at the interface. The model incorporates gas generation, turbulent dispersion, and interfacial reactions within a two-dimensional axisymmetric computational domain. Although the slag is initially quiescent and the resulting weak flow appears laminar, a purely laminar assumption fails to reproduce the experimentally measured FeO consumption and CO evolution. The results show that bubble-induced turbulence is essential, as it significantly enhances mass transfer and interfacial reaction rates near the graphite surface. Model predictions were validated against experimental data.</p>

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Eulerian Two-Fluid Modeling of Iron Oxide (FeO) Reduction and Gas Evolution on Graphite in Smelting Slag

  • E. Karimi-Sibaki,
  • A. Vakhrushev,
  • M. Wu,
  • J. Bohacek,
  • A. Kharicha

摘要

A multiphase Eulerian two-fluid model was developed to simulate the reduction of FeO on a graphite surface immersed in a CaO-SiO2-FeO smelting slag. Three phases are considered: the primary slag melt, containing FeO as the sole reactive species; CO gas bubbles generated by the reduction reaction; and iron particles formed at the interface. The model incorporates gas generation, turbulent dispersion, and interfacial reactions within a two-dimensional axisymmetric computational domain. Although the slag is initially quiescent and the resulting weak flow appears laminar, a purely laminar assumption fails to reproduce the experimentally measured FeO consumption and CO evolution. The results show that bubble-induced turbulence is essential, as it significantly enhances mass transfer and interfacial reaction rates near the graphite surface. Model predictions were validated against experimental data.