<p>Due to the positive effects of Si, graphite, and silicon carbide on sinterability, they were selected as additives, and their effects on the microstructure and mechanical properties of (HfTaZrTiV)C high-entropy ceramic were investigated. For this purpose, (HfTaZrTiV)C ceramics without additives (HZTTV) and with graphite and Si additives (HZTTV/SiGr) were sintered by the spark plasma sintering (SPS) method at 2000°C. The relative density of the samples was measured by the Archimedes method. Phase identification was done using X-ray diffraction analysis (XRD). Microstructural studies and elemental distribution analysis were carried out using field-emission scanning electron microscopy (FE-SEM) and energy-dispersive spectroscopy (EDS), respectively. The XRD results showed that a solid solution formed in both samples. Also, the grain size measurement showed that both samples have submicron grain sizes of 0.73 ± 0.2 and 0.76 ± 0.3 for HZTTV/SiGr and HZTTV, respectively. In the HZTTV/SiGr sample, the relative density, hardness, and fracture toughness are significantly higher than those of the HZTTV sample, reaching 99.7%, 32.5 GPa, and 5.8&#xa0;MPa m<sup>0.5</sup> from 95.8%, 21.5 GPa, and 4.3&#xa0;MPa m<sup>0.5,</sup> respectively. The dominant toughening mechanisms in HZTTV/SiGr were crack deflection and crack branching.</p>

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A Novel (HfTaZrTiV) C High-Entropy Ceramic with Submicron Grains: Role of Graphite and Si Additives

  • Davoud Habibnia,
  • Zohre Balak

摘要

Due to the positive effects of Si, graphite, and silicon carbide on sinterability, they were selected as additives, and their effects on the microstructure and mechanical properties of (HfTaZrTiV)C high-entropy ceramic were investigated. For this purpose, (HfTaZrTiV)C ceramics without additives (HZTTV) and with graphite and Si additives (HZTTV/SiGr) were sintered by the spark plasma sintering (SPS) method at 2000°C. The relative density of the samples was measured by the Archimedes method. Phase identification was done using X-ray diffraction analysis (XRD). Microstructural studies and elemental distribution analysis were carried out using field-emission scanning electron microscopy (FE-SEM) and energy-dispersive spectroscopy (EDS), respectively. The XRD results showed that a solid solution formed in both samples. Also, the grain size measurement showed that both samples have submicron grain sizes of 0.73 ± 0.2 and 0.76 ± 0.3 for HZTTV/SiGr and HZTTV, respectively. In the HZTTV/SiGr sample, the relative density, hardness, and fracture toughness are significantly higher than those of the HZTTV sample, reaching 99.7%, 32.5 GPa, and 5.8 MPa m0.5 from 95.8%, 21.5 GPa, and 4.3 MPa m0.5, respectively. The dominant toughening mechanisms in HZTTV/SiGr were crack deflection and crack branching.