<p>This paper systematically investigates the influence of varying carbon contents on the microstructure and properties of nitrogen-containing Cr13-type corrosion-resistant die steel in quenched and tempered states. The results indicate that the steel microstructure after quenching at 1030&#xa0;°C mainly consists of martensite and undissolved carbides. As carbon content increases, martensite morphology gradually transitions from lath to cryptocrystalline martensite, accompanied by reduced grain size, and undissolved M<sub>23</sub>C<sub>6</sub> carbides maintain constant size but increase in quantity. Elevated carbon content raises steel hardness from 50.8 to 56.3 HRC, reduces toughness from 5.4 to 4.4&#xa0;J, causes brittle fracture of all specimens under impact loading, and degrades pitting corrosion resistance. During 600&#xa0;°C tempering, numerous nanoscale M<sub>23</sub>C<sub>6</sub> carbides precipitate. With carbon content increasing from 0.15% to 0.19%, tensile strength rises from 993 to 1047&#xa0;MPa; further increases to 0.24% reduce it to 1032&#xa0;MPa. Meanwhile, toughness continuously declines from 12 to 7.5&#xa0;J. Correspondingly, the fracture mode shifts from purely ductile to mixed ductile-brittle. Owing to the synergistic effects of carbon and nitrogen, the steel with 0.19% carbon content exhibits superior mechanical properties at a fixed nitrogen content of 0.1%</p>

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Effect of Carbon Content on Microstructure and Properties of Nitrogen-Containing Cr13-Type Corrosion-Resistant Die Steel

  • Bao-Shuai Chu,
  • Mei Xu,
  • Wen Yang

摘要

This paper systematically investigates the influence of varying carbon contents on the microstructure and properties of nitrogen-containing Cr13-type corrosion-resistant die steel in quenched and tempered states. The results indicate that the steel microstructure after quenching at 1030 °C mainly consists of martensite and undissolved carbides. As carbon content increases, martensite morphology gradually transitions from lath to cryptocrystalline martensite, accompanied by reduced grain size, and undissolved M23C6 carbides maintain constant size but increase in quantity. Elevated carbon content raises steel hardness from 50.8 to 56.3 HRC, reduces toughness from 5.4 to 4.4 J, causes brittle fracture of all specimens under impact loading, and degrades pitting corrosion resistance. During 600 °C tempering, numerous nanoscale M23C6 carbides precipitate. With carbon content increasing from 0.15% to 0.19%, tensile strength rises from 993 to 1047 MPa; further increases to 0.24% reduce it to 1032 MPa. Meanwhile, toughness continuously declines from 12 to 7.5 J. Correspondingly, the fracture mode shifts from purely ductile to mixed ductile-brittle. Owing to the synergistic effects of carbon and nitrogen, the steel with 0.19% carbon content exhibits superior mechanical properties at a fixed nitrogen content of 0.1%