Scholarlink

<p>Zeolitic Imidazolate Framework-14 (ZIF-14) was successfully synthesized for the first time from zinc chloride with high yield in an environmentally friendly solvent at room temperature. The effects of precursors, solvents, additives, reaction time, and temperature were systematically investigated. A scalable synthesis process for ZIF-14 was also developed, demonstrating good reproducibility. The synthesized ZIF-14 was characterized using x-ray powder diffraction (XRD), fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), differential thermal analysis<b> (</b>DTA), thermal gravimetric analysis (TGA), and nitrogen adsorption–desorption isotherms methods. The results confirmed that ZIF-14 synthesized under optimal conditions exhibited a specific surface area (BET) of 830 m<sup>2</sup>/g, thermal stability up to 300&#xa0;°C, a particle size of 6.5&#xa0;µm, and a yield of 74.0%. The synthesized ZIF-14 was employed as a catalyst for the synthesis of 1-Methoxy-2-propanol (1-MP) from Propylene Oxide (PO) and Methanol (CH<sub>3</sub>OH), yielding excellent results. The PO conversion reached 100%, and the 1-MP selectivity was 98.6% after 6&#xa0;h at 110&#xa0;°C.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Synthesis of Zeolitic Imidazolate Framework-14 from Zinc Chloride and its Application as a Catalyst for the Synthesis of 1-Methoxy-2-Propanol

  • 期刊论文

  • 发表日期：

    2026年1月21日

查看全文
  • Ta Ngoc Don,
  • Ta Ngoc Thien Huy,
  • Tran Anh Vy,
  • Ta Ngoc Hung,
  • Le Van Duong

摘要

Zeolitic Imidazolate Framework-14 (ZIF-14) was successfully synthesized for the first time from zinc chloride with high yield in an environmentally friendly solvent at room temperature. The effects of precursors, solvents, additives, reaction time, and temperature were systematically investigated. A scalable synthesis process for ZIF-14 was also developed, demonstrating good reproducibility. The synthesized ZIF-14 was characterized using x-ray powder diffraction (XRD), fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), differential thermal analysis (DTA), thermal gravimetric analysis (TGA), and nitrogen adsorption–desorption isotherms methods. The results confirmed that ZIF-14 synthesized under optimal conditions exhibited a specific surface area (BET) of 830 m2/g, thermal stability up to 300 °C, a particle size of 6.5 µm, and a yield of 74.0%. The synthesized ZIF-14 was employed as a catalyst for the synthesis of 1-Methoxy-2-propanol (1-MP) from Propylene Oxide (PO) and Methanol (CH3OH), yielding excellent results. The PO conversion reached 100%, and the 1-MP selectivity was 98.6% after 6 h at 110 °C.