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<p>High-entropy rare-earth tantalates have potential for use in thermal barrier coatings, but current research has focused mostly on powder or bulk materials instead of coatings. In this work, atmospheric plasma spraying technology was employed to prepare novel high-entropy rare-earth tantalate (Nd<sub>0.2</sub>Dy<sub>0.2</sub>Ho<sub>0.2</sub>Y<sub>0.2</sub>Er<sub>0.2</sub>)TaO<sub>4</sub> (HE-RETaO<sub>4</sub>) coatings on the surface of nickel-based alloys. The as-sprayed HE-RETaO<sub>4</sub> powders undergo a ferroelastic phase transition from the monoclinic (m) phase to the metastable tetragonal (t′) phase during the spraying process. Owing to the influence the cationic radii of multispecies HE-RETaO<sub>4</sub>, its phase transition temperature is lower than that of YTaO<sub>4</sub>, leading to the formation of a ferroelastic domain toughened structure at lower temperatures. Under the plasma flame assessment at 1200 and 1300&#xa0;°C, the insulation temperatures of the HE-RETaO<sub>4</sub> coatings are 220 and 200&#xa0;°C, respectively. The sluggish diffusion of HE-RETaO<sub>4</sub> hinders diffusion of elements, ultimately engendering a profusion of equiaxed grains with comparable aspect ratios and a substantial divergence in energy between intragranular regions and boundaries. In addition, the microcracks generated within the HE-RETaO<sub>4</sub> coatings rapidly expand along the high-energy grain boundaries of the equiaxed grains, eventually leading to mechanical delamination and coating failure. This work provides a powerful theoretical basis for the application of HE-RETaO<sub>4</sub> as a high-temperature protective material.</p>

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High-Temperature Thermal Protective Performance of High-Entropy Rare-Earth Tantalate (Nd0.2Dy0.2Ho0.2Y0.2Er0.2)TaO4 Coating Deposited By Atmospheric Plasma Spraying

  • 期刊论文

  • 发表日期：

    2025年7月29日

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  • Yulong Zhang,
  • Jinpeng Zhu,
  • Jiayi Zheng,
  • Kai Wang,
  • Yujing Li,
  • Kaijun Yang,
  • Mingliang Li,
  • Hailong Wang,
  • Jilin He

摘要

High-entropy rare-earth tantalates have potential for use in thermal barrier coatings, but current research has focused mostly on powder or bulk materials instead of coatings. In this work, atmospheric plasma spraying technology was employed to prepare novel high-entropy rare-earth tantalate (Nd0.2Dy0.2Ho0.2Y0.2Er0.2)TaO4 (HE-RETaO4) coatings on the surface of nickel-based alloys. The as-sprayed HE-RETaO4 powders undergo a ferroelastic phase transition from the monoclinic (m) phase to the metastable tetragonal (t′) phase during the spraying process. Owing to the influence the cationic radii of multispecies HE-RETaO4, its phase transition temperature is lower than that of YTaO4, leading to the formation of a ferroelastic domain toughened structure at lower temperatures. Under the plasma flame assessment at 1200 and 1300 °C, the insulation temperatures of the HE-RETaO4 coatings are 220 and 200 °C, respectively. The sluggish diffusion of HE-RETaO4 hinders diffusion of elements, ultimately engendering a profusion of equiaxed grains with comparable aspect ratios and a substantial divergence in energy between intragranular regions and boundaries. In addition, the microcracks generated within the HE-RETaO4 coatings rapidly expand along the high-energy grain boundaries of the equiaxed grains, eventually leading to mechanical delamination and coating failure. This work provides a powerful theoretical basis for the application of HE-RETaO4 as a high-temperature protective material.