Effect of Low CdS Incorporation on the Humidity Sensing Characteristics of TiO2 Thick-Film Sensors
摘要
Our aim is to study, synthesize and characterize titanium dioxide (TiO2) and cadmium sulfide (CdS)-doped titanium dioxide (CdS-TiO2) thick-film sensors with varying CdS concentrations (1–2 wt.%) and to evaluate their humidity-sensing performance through impedance analysis under controlled relative humidity conditions. The TiO2 and 1-2 wt.% CdS-doped TiO2 thick-film sensors were fabricated using a cheap and simple method. TiO2 and CdS-TiO2 pastes were prepared by mixing of acetic acid with Lebolin solvent, deposited onto alumina substrates, and annealed at 200 °C. The films were characterized using x-ray diffraction (XRD), atomic force microscopy (AFM), and field-emission scanning electron microscopy (FESEM) to examine their microstructural properties. Humidity-sensing performance was evaluated through impedance measurements at various frequencies under controlled relative humidity conditions. The incorporation of CdS into TiO2 significantly enhanced electrical conductivity and sensing performance. The 1 wt.% CdS-TiO2 sensor exhibited the highest average sensitivity (4.19 MΩ/%RH at 50 Hz) across all tested frequencies, while the 2 wt.% CdS-TiO2 sensor demonstrated faster response (14.1 sec.) and recovery times (21.87 sec.). These results indicate that CdS-TiO2 nanocomposites are promising materials for humidity sensing applications.