Inhibitory Effect of Electroless Ni-P Plating of Aluminum Radiator on Scaling on Grading Electrode in High-Voltage Direct Current Converter
摘要
Corrosion of aluminum radiators in high-voltage direct current (HVDC) converter valves induces scaling on grading electrodes. To address this, radiator surfaces were treated with electroless Ni-P plating baths incorporating various additive systems. Systematic corrosion resistance testing, combined with phase composition and microstructural characterization of the Ni-P coatings, confirmed their significant enhancement of the aluminum alloy’s corrosion resistance in simulated internal cooling water. Cyclic flushing simulation tests further revealed that grading electrode scaling primarily originates from radiator corrosion, with preferential accumulation occurring at the current outflow region. Radiators subjected to electroless Ni-P treatment exhibited substantially reduced corrosion rates under identical applied voltage conditions. Consequently, the scaling rate on grading electrodes decreased by 95.5%. These results demonstrate that applying electroless Ni-P coatings to aluminum alloy radiators in converter valves effectively mitigates both radiator corrosion and associated grading electrode scaling.