<p>The influence of heat treatment on the microstructure and corrosion behavior of Al<sub>0.3</sub>Co<sub>0.25</sub>CrFeNi high entropy alloy were comprehensively investigated. The results demonstrate that the increased temperature of heat treatment from 500 to 1200&#xa0;°C induces the phase transition from a double-phase (FCC + BCC) structure to a single-phase FCC structure, thereby enhancing the corrosion resistance of alloy due to the redissolution of interdendritic structures. However, the precipitation of (Al, Ni)-rich L1<sub>2</sub> ordered phase after heat treatment at 800&#xa0;°C deteriorates corrosion resistance. Selective corrosion of the (Al, Ni)-rich phases dominates the localized corrosion mechanism in heat-treated Al<sub>0.3</sub>Co<sub>0.25</sub>CrFeNi high-entropy alloy.</p>

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Effect of Heat Treatment on Microstructure and Corrosion Behavior of Al0.3Co0.25CrFeNi High Entropy Alloys

  • Zequn Zhang,
  • Shujie He,
  • Guoqing Duan,
  • Haibo Zhou,
  • Qijuan Dong,
  • Bowei Zhang,
  • Yageng Li,
  • Junsheng Wu

摘要

The influence of heat treatment on the microstructure and corrosion behavior of Al0.3Co0.25CrFeNi high entropy alloy were comprehensively investigated. The results demonstrate that the increased temperature of heat treatment from 500 to 1200 °C induces the phase transition from a double-phase (FCC + BCC) structure to a single-phase FCC structure, thereby enhancing the corrosion resistance of alloy due to the redissolution of interdendritic structures. However, the precipitation of (Al, Ni)-rich L12 ordered phase after heat treatment at 800 °C deteriorates corrosion resistance. Selective corrosion of the (Al, Ni)-rich phases dominates the localized corrosion mechanism in heat-treated Al0.3Co0.25CrFeNi high-entropy alloy.