<p>Parts made from H13 steel are widely used in harsh working environment subjected to severe friction and wear under heavy loads at elevated temperature, reducing greatly its service life. To enhance the wear resistance of these components, three micro-nanostructure Al<sub>2</sub>O<sub>3</sub>-NiCr coatings contained nano rare-earth oxides (CeO<sub>2</sub>, La<sub>2</sub>O<sub>3</sub>, and Sm<sub>2</sub>O<sub>3</sub>) were prepared on the surface of H13 steel using laser cladding technology. The effects of nano rare-earth oxides on the microstructure, wettability, microhardness, and wear resistance of the micro-nanostructure Al<sub>2</sub>O<sub>3</sub>-NiCr coatings were investigated, and the rare-earth modification mechanisms were stated. Results show that the micro-nanostructure Al<sub>2</sub>O<sub>3</sub>-NiCr coatings primarily is composed of dense aggregates consisted of micron-sized and nano-sized Al<sub>2</sub>O<sub>3</sub> particles, with smaller particles filling voids among larger particles. The microstructure of the coating with nano rare-earth oxide additions is refined compared to the coatings without such additions. Adding nano rare-earth oxides significantly improved Al<sub>2</sub>O<sub>3</sub> ceramics and NiCr alloy wettability. Further, the results demonstrate that influences of nano Sm<sub>2</sub>O<sub>3</sub> oxide on the microstructure and wear-resistant properties are superior to CeO<sub>2</sub> and La<sub>2</sub>O<sub>3</sub> oxides.</p>

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Influence of Nano Rare-Earth Oxides on the Microstructure and Wear Resistance of Laser Clad Micro-nanostructure Al2O3-NiCr Coating

  • Lingyu Meng,
  • Ming Hu,
  • Hanqing Zhao,
  • Peng Lv,
  • Amin Wang

摘要

Parts made from H13 steel are widely used in harsh working environment subjected to severe friction and wear under heavy loads at elevated temperature, reducing greatly its service life. To enhance the wear resistance of these components, three micro-nanostructure Al2O3-NiCr coatings contained nano rare-earth oxides (CeO2, La2O3, and Sm2O3) were prepared on the surface of H13 steel using laser cladding technology. The effects of nano rare-earth oxides on the microstructure, wettability, microhardness, and wear resistance of the micro-nanostructure Al2O3-NiCr coatings were investigated, and the rare-earth modification mechanisms were stated. Results show that the micro-nanostructure Al2O3-NiCr coatings primarily is composed of dense aggregates consisted of micron-sized and nano-sized Al2O3 particles, with smaller particles filling voids among larger particles. The microstructure of the coating with nano rare-earth oxide additions is refined compared to the coatings without such additions. Adding nano rare-earth oxides significantly improved Al2O3 ceramics and NiCr alloy wettability. Further, the results demonstrate that influences of nano Sm2O3 oxide on the microstructure and wear-resistant properties are superior to CeO2 and La2O3 oxides.