<p>In order to improve the overall performance of 6061 aluminum alloy, this paper adds La<sub>2</sub>O<sub>3</sub> to the electrolyte for micro-arc oxidation and studies the effect of lanthanum oxide concentration on the structure and performance of the film. The results show that the basic phases of the films are Al, <i>α</i>-Al<sub>2</sub>O<sub>3</sub>, <i>γ</i>-Al<sub>2</sub>O<sub>3</sub>, SiO<sub>2</sub> and mullite. The micro-arc oxidized film layer is a porous structure, and the corrosive medium and the substrate form a double electrical layer structure, which causes corrosion. The addition of La<sub>2</sub>O<sub>3</sub> improves the densification of the film layer, and the holes or cracks are reduced, but too much La<sub>2</sub>O<sub>3</sub> will accumulate on the surface, causing the porosity to increase. Therefore, with the increase of La<sub>2</sub>O<sub>3</sub> concentration, the porosity and roughness of the film layer decrease and then increase, and the thickness hardness and corrosion resistance increase and then decrease. When the dosage of La<sub>2</sub>O<sub>3</sub> is 1.0&#xa0;g/L, the thickness and hardness are the largest, the roughness is the smallest, the corrosion resistance is the best, and the self-corrosion current density is 9.986 × 10<sup>-10</sup>&#xa0;A/cm<sup>2</sup>. When the dosage of La<sub>2</sub>O<sub>3</sub> is 1.0&#xa0;g/L, the overall performance of the micro-arc oxidation film is the best.</p>

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Effect of Lanthanum Oxide on Microstructure and Corrosion Properties of 6061 Aluminum Alloy Micro-arc Oxide Film

  • Defen Zhang,
  • Yang Lv,
  • Yun Ran,
  • Qingzhen Ran,
  • Peigang Jiang,
  • Xiaowen Chen

摘要

In order to improve the overall performance of 6061 aluminum alloy, this paper adds La2O3 to the electrolyte for micro-arc oxidation and studies the effect of lanthanum oxide concentration on the structure and performance of the film. The results show that the basic phases of the films are Al, α-Al2O3, γ-Al2O3, SiO2 and mullite. The micro-arc oxidized film layer is a porous structure, and the corrosive medium and the substrate form a double electrical layer structure, which causes corrosion. The addition of La2O3 improves the densification of the film layer, and the holes or cracks are reduced, but too much La2O3 will accumulate on the surface, causing the porosity to increase. Therefore, with the increase of La2O3 concentration, the porosity and roughness of the film layer decrease and then increase, and the thickness hardness and corrosion resistance increase and then decrease. When the dosage of La2O3 is 1.0 g/L, the thickness and hardness are the largest, the roughness is the smallest, the corrosion resistance is the best, and the self-corrosion current density is 9.986 × 10-10 A/cm2. When the dosage of La2O3 is 1.0 g/L, the overall performance of the micro-arc oxidation film is the best.