Scholarlink

<p>A new organic–inorganic hybrid salt, bis(2-carboxypyridin-1-ium) hexachlorostannate(IV) dihydrate ([2-CpyH]<sub>2</sub>[SnCl<sub>6</sub>]), was synthesized and structurally characterized through single-crystal x-ray diffraction, Hirshfeld surface analysis, and bond valence sum calculations. The compound exhibits a robust three-dimensional hydrogen-bonded framework and columnar packing of [SnCl<sub>6</sub>]<sup>2−</sup> octahedra, which collectively enhance structural stability and electronic polarization. Optical studies reveal a wide bandgap of 4.28&#xa0;eV and strong blue-violet emission at 386&#xa0;nm, indicating potential applicability in UV sensing and related photonic technologies. Z-scan measurements demonstrate a notable third-order nonlinear optical susceptibility, χ<sup>(3)</sup> = 1.75 x 10<sup>−11</sup> esu, arising from combined reverse saturable absorption and self-defocusing behaviour, confirming the suitability of the material for optical limiting and photonic switching applications. Dielectric measurements show pronounced dispersion at low frequencies and stable, low-loss behaviour at high frequencies, supported by efficient dipolar orientation and interfacial polarization. AC conductivity analysis reveals a transition from defect-mediated conduction at low frequencies to hopping-dominated transport at higher frequencies. These combined structural, optical, and dielectric properties highlight [2-CpyH]<sub>2</sub>[SnCl<sub>6</sub>] as a promising multifunctional material for photonic, optoelectronic, and dielectric device applications.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Structural, Optical, Dielectric, and Third-Order Nonlinear Properties of a New Organic–Inorganic Hybrid: Bis(2-Carboxypyridin-1-Ium) Hexachlorostannate(IV) Dihydrate

  • 期刊论文

  • 发表日期：

    2026年1月14日

查看全文
  • Elyorbek Shonazar ugli Samandarov,
  • Pirnazar Kodamboevich Kodamboev,
  • Aziz Bakhtiyarovich Ibragimov,
  • Rajamanickam Duraisamy,
  • Guganathan Loganathan,
  • Ikrom Iskandarovich Abdullaev,
  • Bakhtiyar Tulaganovich Ibragimov,
  • Sivaprakasam Anbazhagan,
  • Yuldosh Yusupboevich Yakubov,
  • Balakrishnan Chellakarungu

摘要

A new organic–inorganic hybrid salt, bis(2-carboxypyridin-1-ium) hexachlorostannate(IV) dihydrate ([2-CpyH]2[SnCl6]), was synthesized and structurally characterized through single-crystal x-ray diffraction, Hirshfeld surface analysis, and bond valence sum calculations. The compound exhibits a robust three-dimensional hydrogen-bonded framework and columnar packing of [SnCl6]2− octahedra, which collectively enhance structural stability and electronic polarization. Optical studies reveal a wide bandgap of 4.28 eV and strong blue-violet emission at 386 nm, indicating potential applicability in UV sensing and related photonic technologies. Z-scan measurements demonstrate a notable third-order nonlinear optical susceptibility, χ(3) = 1.75 x 10−11 esu, arising from combined reverse saturable absorption and self-defocusing behaviour, confirming the suitability of the material for optical limiting and photonic switching applications. Dielectric measurements show pronounced dispersion at low frequencies and stable, low-loss behaviour at high frequencies, supported by efficient dipolar orientation and interfacial polarization. AC conductivity analysis reveals a transition from defect-mediated conduction at low frequencies to hopping-dominated transport at higher frequencies. These combined structural, optical, and dielectric properties highlight [2-CpyH]2[SnCl6] as a promising multifunctional material for photonic, optoelectronic, and dielectric device applications.