<p>High-Cr and Ti-bearing ferritic stainless steel (Ti-FSS) has superior corrosion resistance compared to other steel grades. Ti-FSS offers not only high corrosion resistance and formability but also superior cleanliness of the cold-rolled sheet. Specifically, the cleanliness of Ti-FSS is improved through vacuum oxygen decarburization (VOD) and ladle treatment (LT) processes. Nevertheless, there are unresolved problems such as large fluctuations in Ti-yield and formation-removal behavior of non-metallic inclusions (NMI) due to factors including Al deoxidation and slag-metal reactions after Ti alloying. Moreover, Mg(Al,Ti)<sub>2</sub>O<sub>4</sub> spinel-type inclusions formed in molten steel after Ti alloying cause nozzle clogging and surface defects in the final products. Therefore, it is essential to design the slag refining process to ensure excellent removal of NMI and optimize deoxidation practice in VOD. In the present study, we investigated the Ti-yield and evolution behavior and number density (ND) of NMI in molten steel according to input conditions of aluminum and titanium in steel as well as TiO<sub>2</sub> and CaF<sub>2</sub> in slag during reactions between Ti-FSS melt and VOD slag. As the TiO<sub>2</sub> content in the slag increased, the Ti-yield in the molten steel and the average Ti<sub>2</sub>O<sub>3</sub> content in the NMI both increased after the addition of titanium. When the Al/Ti input ratio increased, the Ti-yield in the molten steel slightly increased. Mg pick-up from the slag also increased with increasing Al/Ti input ratio, resulting in increased MgO content in NMI, and thus, spinel-type inclusions were modified into MgO particles. When the CaF<sub>2</sub> content in the slag increased, the total removal rate of NMI increased due to a decrease in slag viscosity, resulting in a concomitant decrease of the number density of NMI in Ti-FSS.</p>

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Evolution Behavior of Non-metallic Inclusions in Al-Killed Ti-Bearing Ferritic Stainless Steel Under VOD Refining Conditions

  • Dong Yul Jung,
  • Yeong Jin Jun,
  • Sung Jin Park,
  • Soo Chang Kang,
  • Joo Hyun Park

摘要

High-Cr and Ti-bearing ferritic stainless steel (Ti-FSS) has superior corrosion resistance compared to other steel grades. Ti-FSS offers not only high corrosion resistance and formability but also superior cleanliness of the cold-rolled sheet. Specifically, the cleanliness of Ti-FSS is improved through vacuum oxygen decarburization (VOD) and ladle treatment (LT) processes. Nevertheless, there are unresolved problems such as large fluctuations in Ti-yield and formation-removal behavior of non-metallic inclusions (NMI) due to factors including Al deoxidation and slag-metal reactions after Ti alloying. Moreover, Mg(Al,Ti)2O4 spinel-type inclusions formed in molten steel after Ti alloying cause nozzle clogging and surface defects in the final products. Therefore, it is essential to design the slag refining process to ensure excellent removal of NMI and optimize deoxidation practice in VOD. In the present study, we investigated the Ti-yield and evolution behavior and number density (ND) of NMI in molten steel according to input conditions of aluminum and titanium in steel as well as TiO2 and CaF2 in slag during reactions between Ti-FSS melt and VOD slag. As the TiO2 content in the slag increased, the Ti-yield in the molten steel and the average Ti2O3 content in the NMI both increased after the addition of titanium. When the Al/Ti input ratio increased, the Ti-yield in the molten steel slightly increased. Mg pick-up from the slag also increased with increasing Al/Ti input ratio, resulting in increased MgO content in NMI, and thus, spinel-type inclusions were modified into MgO particles. When the CaF2 content in the slag increased, the total removal rate of NMI increased due to a decrease in slag viscosity, resulting in a concomitant decrease of the number density of NMI in Ti-FSS.