Sustainable Steel Refining by Hydrogen Plasma: Effect of Impurities on Desulfurization of Liquid Iron
摘要
The hydrogen-based steelmaking process toward carbon neutrality also produces a considerable amount of slag. This study aims to see the effect of impurities in the liquid metal during desulfurization by hydrogen plasma toward sustainable steelmaking with the least or no slag generation. A laboratory scale transferred arc plasma furnace was used to study sulfur removal from liquid iron, varying H2–Ar gas mixtures up to 70 minutes of exposure. Binary (Fe–S), Ternary (Fe–C–S, Fe–Mn–S, and Fe–Si–S), and multicomponent systems (Fe–C–Si–Mn–S–P) were prepared for this study. Observation made that maximum desulfurization achieved by 1 L/minute H2 + 1 L/minute Ar gas mixture flow rate. Fe–S system attained the highest sulfur removal (~ 87 pct) followed by Fe–C–Si–Mn–S–P (~ 81 pct), Fe–C–S (~ 81 pct), Fe–Mn–S (~ 66 pct), and Fe–Si–S (~ 46 pct). In binary systems, due to the absence of any other impurities, the removal rate was highest followed by ternary and multicomponent systems. As the present system was not fully airtight, the air infiltration caused the formation of a thin slag layer above the melt surface during the preparation of Fe–Mn–S and Fe–Si–S ternary melt, which restricted the effective reaction of hydrogen plasma resulting in less desulfurization.