Characteristics and source apportionment of atmospheric fine particulate-bound mercury (PBM2.5) in abandoned mercury mining areas in southwestern China
摘要
Atmospheric fine particulate-bound mercury (PBM2.5) plays an important role in the biogeochemical behavior of atmospheric Hg. This study conducted seasonal sampling of PM2.5 in a large, abandoned Hg mining area (Wanshan, WS) and an urban area (Bijiang, BJ) during the COVID-19 pandemic (2020–2023), aiming to elucidate the concentration levels, spatiotemporal distribution characteristics and potential sources of PBM2.5. The results indicate that implementing epidemic control measures had a positive effect on reducing PM2.5 concentrations. Both BJ and WS exhibited distinct seasonal variations in PM2.5, with higher concentrations in winter and lower levels in summer. PBM2.5 exhibited distinct seasonal characteristics, with higher concentrations in winter and spring, and lower levels in summer. During the epidemic prevention and control period, PBM2.5 concentrations decreased significantly at BJ, whereas at WS they also declined but remained relatively high. The interannual PBM2.5 concentrations at BJ and WS ranged from 194 (280) to 490 (590) pg·m–3 and from 404 (465) to 804 (956) pg·m–3, respectively. Source apportionment revealed that historical Hg mining activities and nearby factories related to Hg recycling were the predominant contributors to PBM2.5. In addition, coal combustion, biomass burning and soil dust were significant contributors to PBM2.5 in the study area. These findings provide essential scientific data for developing targeted environmental management policies for abandoned Hg mining areas.