Rare earth elements and C and O isotope compositions of modern lake Fe–Mn nodules from Lake Krasnoe, Karelian Isthmus, North-West Russia
摘要
Rare earth elements (REEs) were studied in ferromanganese nodules and bivalve shell carbonates from Lake Krasnoe (Karelian Isthmus, West Russia). This lake is a model example of modern lacustrine manganese ore genesis. The results revealed important features of the formation of modern manganese ores in the diagenesis zone of lake sediments: (1) carbonates of bivalve shells and the Mn-oxide crusts on them show very strong positive Eu anomalies but insignificant negative Ce anomalies; (2) manganese oxide nodules exhibit strong negative Eu anomalies; therefore, the negative cerium anomalies are insufficient; (3) REEs in the studied Fe–Mn-ore nodules are associated with organic matter (Corg), phosphates and iron hydroxides; (4) a positive correlation between carbon (δ13C, ‰, V-PDB) and oxygen isotopes (δ18O, ‰; SMOW) versus Ce/Ce* is observed. The authors believe that the obtained regularities in the distribution of REE content, Eu and Ce anomalies, and C- and O-isotope composition (δ13C, δ18O) result from changes in the physicochemical conditions in the ore body lake sediments during early diagenesis, which oxidize organic matter (Corg), and active participation of microorganisms in manganese ore formation.