<p>We have described in detail the effects of nano-SiO<sub>2</sub>, nano-CaCO<sub>3</sub>, carbon nanotubes, and nano-Al<sub>2</sub>O<sub>3</sub> on geopolymer concrete from the perspectives of macro mechanics and microstructure. The existing research results show that the mechanism of nano-materials on geopolymer concrete mainly includes the filling effect, nucleation effect, and bridging effect, the appropriate amount of nano-materials can be used as fillers to reduce the porosity of geopolymer concrete, and can also react with Ca(OH)<sub>2</sub> to produce C-S-H gel, thereby improving the mechanical properties of geopolymer concrete. The optimum content of nano-SiO<sub>2</sub> is between 1.0% and 2.0%. The optimum content of nano-CaCO<sub>3</sub> is between 2.0% and 3.0%. The optimum content of carbon nanotubes is between 0.1% and 0.2%. The optimum content of nano-Al<sub>2</sub>O<sub>3</sub> is between 1.0% and 2.0%. The main problems existing in the research and application of nanomaterial-modified geopolymer concrete are summarized, which lays a foundation for the further application of nanomaterial in geopolymer concrete.</p>

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Macro-mechanics and Microstructure of Nanomaterial-modified Geopolymer Concrete: A Comprehensive Review

  • Tao Wang,
  • Xiangqian Fan,
  • Changsheng Gao,
  • Chiyu Qu

摘要

We have described in detail the effects of nano-SiO2, nano-CaCO3, carbon nanotubes, and nano-Al2O3 on geopolymer concrete from the perspectives of macro mechanics and microstructure. The existing research results show that the mechanism of nano-materials on geopolymer concrete mainly includes the filling effect, nucleation effect, and bridging effect, the appropriate amount of nano-materials can be used as fillers to reduce the porosity of geopolymer concrete, and can also react with Ca(OH)2 to produce C-S-H gel, thereby improving the mechanical properties of geopolymer concrete. The optimum content of nano-SiO2 is between 1.0% and 2.0%. The optimum content of nano-CaCO3 is between 2.0% and 3.0%. The optimum content of carbon nanotubes is between 0.1% and 0.2%. The optimum content of nano-Al2O3 is between 1.0% and 2.0%. The main problems existing in the research and application of nanomaterial-modified geopolymer concrete are summarized, which lays a foundation for the further application of nanomaterial in geopolymer concrete.