Transition-Resolved Renormalization of the Excitonic Hierarchy in Hybrid Nanocrystal–Plasmonic Systems
摘要
This study develops a Transition-Resolved Renormalization Framework for separating intrinsic excitonic structure from environment-induced electrodynamic effects in hybrid nanocrystal–plasmonic systems. TD-DFT results for CdSe–ZnS and published atomistic-pseudopotential data for an InP reference system are used as independent electronic-structure inputs. For CdSe–ZnS, four resolved bands exhibit a common displacement of 13.8 ± 1.0 nm, corresponding to an effective mean energy correction of 64 ± 11 meV. Independently, the developed interface relation yields 63.44 meV at the nominal emitter–surface separation