<p>High performance label free localized surface plasmon resonance (LSPR) sensors require resonances that are both sensitive to refractive-index changes and sufficiently narrow for reliable spectral tracking. In this work, a diamond-core/silver-shell nanorod is investigated as a compact refractive-index sensor using three-dimensional finite-element simulations. The nanorod length <InlineEquation ID="IEq1"> <EquationSource Format="TEX">\(L=30\text {--}70~\textrm{nm}\)</EquationSource> </InlineEquation>, core radius <InlineEquation ID="IEq2"> <EquationSource Format="TEX">\(r=4\text {--}12~\textrm{nm}\)</EquationSource> </InlineEquation>, and silver-shell thickness <InlineEquation ID="IEq3"> <EquationSource Format="TEX">\(t=4\text {--}12~\textrm{nm}\)</EquationSource> </InlineEquation> are varied for surrounding refractive indices of <InlineEquation ID="IEq4"> <EquationSource Format="TEX">\(n_\textrm{env}=1.33\text {--}1.45\)</EquationSource> </InlineEquation>, with wavelength-dependent optical constants assigned to both diamond and silver. All three geometry sweeps demonstrate nearly linear red shifts of the longitudinal plasmon resonance with increasing <InlineEquation ID="IEq5"> <EquationSource Format="TEX">\(n_\textrm{env}\)</EquationSource> </InlineEquation>. Increasing the nanorod length raises the bulk sensitivity from <InlineEquation ID="IEq6"> <EquationSource Format="TEX">\(175\)</EquationSource> </InlineEquation> to <InlineEquation ID="IEq7"> <EquationSource Format="TEX">\(400~\mathrm {nm/RIU}\)</EquationSource> </InlineEquation>, whereas the best length-dependent average figure of merit (FOM) occurs at <InlineEquation ID="IEq8"> <EquationSource Format="TEX">\(L=60~\textrm{nm}\)</EquationSource> </InlineEquation> because further elongation broadens the resonance. Reducing the core radius improves environmental coupling, giving <InlineEquation ID="IEq9"> <EquationSource Format="TEX">\(400~\mathrm {nm/RIU}\)</EquationSource> </InlineEquation> for <InlineEquation ID="IEq10"> <EquationSource Format="TEX">\(r=4\text {--}6~\textrm{nm}\)</EquationSource> </InlineEquation>. In the shell-thickness sweep, <InlineEquation ID="IEq11"> <EquationSource Format="TEX">\(t=4~\textrm{nm}\)</EquationSource> </InlineEquation> provides the best sensitivity–linewidth balance, with <InlineEquation ID="IEq12"> <EquationSource Format="TEX">\(375~\mathrm {nm/RIU}\)</EquationSource> </InlineEquation> and an average FOM of <InlineEquation ID="IEq13"> <EquationSource Format="TEX">\(21.47\)</EquationSource> </InlineEquation>. For the representative high-response geometry <InlineEquation ID="IEq14"> <EquationSource Format="TEX">\(L=70~\textrm{nm}\)</EquationSource> </InlineEquation>, <InlineEquation ID="IEq15"> <EquationSource Format="TEX">\(r=4~\textrm{nm}\)</EquationSource> </InlineEquation>, and <InlineEquation ID="IEq16"> <EquationSource Format="TEX">\(t=4~\textrm{nm}\)</EquationSource> </InlineEquation>, the normalized field map at <InlineEquation ID="IEq17"> <EquationSource Format="TEX">\(n_\textrm{env}=1.33\)</EquationSource> </InlineEquation> and <InlineEquation ID="IEq18"> <EquationSource Format="TEX">\(\lambda =498~\textrm{nm}\)</EquationSource> </InlineEquation> shows end-cap hotspots with <InlineEquation ID="IEq19"> <EquationSource Format="TEX">\(|E|/|E_0|\approx 18.4\)</EquationSource> </InlineEquation>. In this work, absorption cross-section is measured in sqaure meter. Within the smooth-interface classical finite-element model used here, long, slender diamond cores with thin silver coatings give the strongest refractive-index response in the investigated parameter range. Experimental realization, however, will require careful control of silver-shell continuity, roughness, oxidation, and size-dependent damping.</p>

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Numerical Investigation of Plasmonic Refractive Index Sensing Using Silver-Coated Diamond Nanorods

  • Muhammad Afzaal,
  • Ajwa Aslam,
  • Aqsa Zulfiqar,
  • Ghulam Abbas,
  • Muhammad Qamar,
  • Muhammad Shahid Imran,
  • Abdul Ghuffar

摘要

High performance label free localized surface plasmon resonance (LSPR) sensors require resonances that are both sensitive to refractive-index changes and sufficiently narrow for reliable spectral tracking. In this work, a diamond-core/silver-shell nanorod is investigated as a compact refractive-index sensor using three-dimensional finite-element simulations. The nanorod length \(L=30\text {--}70~\textrm{nm}\) , core radius \(r=4\text {--}12~\textrm{nm}\) , and silver-shell thickness \(t=4\text {--}12~\textrm{nm}\) are varied for surrounding refractive indices of \(n_\textrm{env}=1.33\text {--}1.45\) , with wavelength-dependent optical constants assigned to both diamond and silver. All three geometry sweeps demonstrate nearly linear red shifts of the longitudinal plasmon resonance with increasing \(n_\textrm{env}\) . Increasing the nanorod length raises the bulk sensitivity from \(175\) to \(400~\mathrm {nm/RIU}\) , whereas the best length-dependent average figure of merit (FOM) occurs at \(L=60~\textrm{nm}\) because further elongation broadens the resonance. Reducing the core radius improves environmental coupling, giving \(400~\mathrm {nm/RIU}\) for \(r=4\text {--}6~\textrm{nm}\) . In the shell-thickness sweep, \(t=4~\textrm{nm}\) provides the best sensitivity–linewidth balance, with \(375~\mathrm {nm/RIU}\) and an average FOM of \(21.47\) . For the representative high-response geometry \(L=70~\textrm{nm}\) , \(r=4~\textrm{nm}\) , and \(t=4~\textrm{nm}\) , the normalized field map at \(n_\textrm{env}=1.33\) and \(\lambda =498~\textrm{nm}\) shows end-cap hotspots with \(|E|/|E_0|\approx 18.4\) . In this work, absorption cross-section is measured in sqaure meter. Within the smooth-interface classical finite-element model used here, long, slender diamond cores with thin silver coatings give the strongest refractive-index response in the investigated parameter range. Experimental realization, however, will require careful control of silver-shell continuity, roughness, oxidation, and size-dependent damping.