<p>Subduction-related Cu-(Au) deposits which represent giant geochemical anomalies of metals and S in the upper crust are commonly associated with arc magmas. However, the fundamental differences between barren and fertile magma producing these deposits still remain highly controversial. In this study, we report the chemical compositions of zircon and silicate melt inclusions (SMIs) from barren arc lavas at eastern Taiwan Island aiming to increase our knowledge on the factors that affect the mineralization potential of arc magma systems. The zircon U-Pb dating shows the magmatism occurred at ~0.7 Ma and the andesitic lava formed at ~900–950°C with a reduced magmatic environment. The plagioclase-hosted SMIs show an andesitic melt composition and variable Cu content features. The calculated H<sub>2</sub>O content of parental melt is ~3–4 wt.%. The evidence presented above suggests that oxidation state (<i>f</i>O<sub>2</sub>) and H<sub>2</sub>O content are probably the key controls of Cu-(Au) fertility of arc magmas. We interpret that a reduced and relatively dry magma may be a potential hinderance to cause the absence of porphyry Cu deposits at the eastern Taiwan Island.</p>

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The factors affecting mineralization potential of arc magma: Insights from silicate melt inclusions and zircon composition of igneous lava at Eastern Taiwan Island

  • Jianping Li,
  • Shitao Zhang,
  • Gaobin Chu,
  • Huayong Chen

摘要

Subduction-related Cu-(Au) deposits which represent giant geochemical anomalies of metals and S in the upper crust are commonly associated with arc magmas. However, the fundamental differences between barren and fertile magma producing these deposits still remain highly controversial. In this study, we report the chemical compositions of zircon and silicate melt inclusions (SMIs) from barren arc lavas at eastern Taiwan Island aiming to increase our knowledge on the factors that affect the mineralization potential of arc magma systems. The zircon U-Pb dating shows the magmatism occurred at ~0.7 Ma and the andesitic lava formed at ~900–950°C with a reduced magmatic environment. The plagioclase-hosted SMIs show an andesitic melt composition and variable Cu content features. The calculated H2O content of parental melt is ~3–4 wt.%. The evidence presented above suggests that oxidation state (fO2) and H2O content are probably the key controls of Cu-(Au) fertility of arc magmas. We interpret that a reduced and relatively dry magma may be a potential hinderance to cause the absence of porphyry Cu deposits at the eastern Taiwan Island.