<p>This is the first report on improving activated carbon fabric (ACF) as an adsorbent for the removal of heavy metals. Magnetic-activated carbon fabric (MACF) was synthesized from waste cotton fabric using a sonosynthesis method with iron salt for removing Cu<sup>2+</sup> and Cd<sup>2+</sup> ions from aqueous solutions. MACFs were characterized with BET, FT-IR, and VSM methods. Optimal conditions for ions removal were pH = 4 for 50 mg L<sup>−1</sup> initial concentration of Cu<sup>2+</sup> and Cd<sup>2+</sup> with 1.5&#xa0;g L<sup>−1</sup> MACF at 20 ± 1&#xa0;°C and 200&#xa0;rpm for 1&#xa0;h. The equilibrium data of adsorption thermodynamics, isotherms, and kinetics of Cu<sup>2+</sup> and Cd<sup>2+</sup> using MACF was investigated. The highest regression values of 0.9998 and 0.9750 were obtained by the Langmuir model among other models for adsorption isotherm using MAFC for Cu<sup>2+</sup> and Cd<sup>2+</sup> respectively. MACF revealed a higher metal removal of 99.2% for Cu<sup>2+</sup> and 94.9% for Cd<sup>2+</sup> for both ions compared to 32% for Cu<sup>2+</sup> and 28% for Cd<sup>2+</sup> using ACF. The results indicate that MACF shows superior performance/cost-effective in removing heavy metal ions compared to granules and powder-activated carbons, which can be easily prepared in different dimensions and removed from the filter/environment, making it a promising alternative for applications requiring enhanced heavy/toxic metal removal from any solution.</p>

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Magnetic-Activated Carbon Fabric for Removal of Copper and Cadmium Ions: Kinetics and Thermodynamics Studies

  • Sepideh Kazemi Moghadam,
  • Fatemeh Dadashian,
  • Majid Montazer,
  • Mohammad Abedi

摘要

This is the first report on improving activated carbon fabric (ACF) as an adsorbent for the removal of heavy metals. Magnetic-activated carbon fabric (MACF) was synthesized from waste cotton fabric using a sonosynthesis method with iron salt for removing Cu2+ and Cd2+ ions from aqueous solutions. MACFs were characterized with BET, FT-IR, and VSM methods. Optimal conditions for ions removal were pH = 4 for 50 mg L−1 initial concentration of Cu2+ and Cd2+ with 1.5 g L−1 MACF at 20 ± 1 °C and 200 rpm for 1 h. The equilibrium data of adsorption thermodynamics, isotherms, and kinetics of Cu2+ and Cd2+ using MACF was investigated. The highest regression values of 0.9998 and 0.9750 were obtained by the Langmuir model among other models for adsorption isotherm using MAFC for Cu2+ and Cd2+ respectively. MACF revealed a higher metal removal of 99.2% for Cu2+ and 94.9% for Cd2+ for both ions compared to 32% for Cu2+ and 28% for Cd2+ using ACF. The results indicate that MACF shows superior performance/cost-effective in removing heavy metal ions compared to granules and powder-activated carbons, which can be easily prepared in different dimensions and removed from the filter/environment, making it a promising alternative for applications requiring enhanced heavy/toxic metal removal from any solution.