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<p>This work presents a sustainable and surfactant-free strategy for synthesizing photocatalytically active tin oxide nanoshells (SnO<sub>2</sub>NSs) via pulsed laser ablation in liquid (PLAL) using chickpea extract as a phytochemical-rich medium. A Q-switched Nd: YAG laser (λ = 1064&#xa0;nm) operating at fluences of 7.53–37.67&#xa0;J/cm<sup>2</sup> generated well-defined crystalline core–shell nanostructures with an average diameter of 13.6 ± 6.3&#xa0;nm, as confirmed by Bio-TEM, SAED, and FTIR analyses. Optical characterization revealed intense UV absorption at ~ 250&#xa0;nm, dual fluorescence bands at ~ 360 and ~ 443&#xa0;nm, and tunable fluorescence quantum yields (0.13–0.24). SnO<sub>2</sub>NSs synthesized at an optimal fluence of 22.6&#xa0;J/cm<sup>2</sup> achieved 96.6% degradation of methylene blue dye (MBD) within 150&#xa0;min under UV irradiation. The superior photocatalytic activity was attributed to nanoshell morphology, surface hydroxylation, and biomolecular capping, which synergistically enhanced charge separation and reactive oxygen species generation. These findings demonstrate the synergy between laser-induced nanostructuring and biofunctional stabilization, establishing SnO<sub>2</sub>NSs an innovative platform for next-generation nanophotocatalysts and advanced wastewater treatment applications.</p>

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Laser-Engineered SnO₂ Nanoshells in Chickpea Phytomatrix: A Green Strategy for Efficient Photocatalytic Dye Degradation

  • 期刊论文

  • 发表日期：

    2025年10月28日

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  • Ahmed Qasim Ubaid,
  • Ali Aqeel Salim,
  • Farzaneh Bayat,
  • Kazem Jamshidi-Ghaleha,
  • Ali Reza Amani-Ghadim

摘要

This work presents a sustainable and surfactant-free strategy for synthesizing photocatalytically active tin oxide nanoshells (SnO2NSs) via pulsed laser ablation in liquid (PLAL) using chickpea extract as a phytochemical-rich medium. A Q-switched Nd: YAG laser (λ = 1064 nm) operating at fluences of 7.53–37.67 J/cm2 generated well-defined crystalline core–shell nanostructures with an average diameter of 13.6 ± 6.3 nm, as confirmed by Bio-TEM, SAED, and FTIR analyses. Optical characterization revealed intense UV absorption at ~ 250 nm, dual fluorescence bands at ~ 360 and ~ 443 nm, and tunable fluorescence quantum yields (0.13–0.24). SnO2NSs synthesized at an optimal fluence of 22.6 J/cm2 achieved 96.6% degradation of methylene blue dye (MBD) within 150 min under UV irradiation. The superior photocatalytic activity was attributed to nanoshell morphology, surface hydroxylation, and biomolecular capping, which synergistically enhanced charge separation and reactive oxygen species generation. These findings demonstrate the synergy between laser-induced nanostructuring and biofunctional stabilization, establishing SnO2NSs an innovative platform for next-generation nanophotocatalysts and advanced wastewater treatment applications.