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<p>The current state of research on heterogeneous systems based on chiral materials for the photocatalytic transformation of organic and inorganic substances is examined. Examples are provided illustrating methods for obtaining photoactive chiral covalent organic frameworks, coordination polymers, inorganic semiconductors, plasmonic catalysts, as well as complex systems integrating achiral photoactive components and chiral cocatalysts. Their application is demonstrated in initiating photocatalytic asymmetric synthesis of valuable organic stereoisomers, degradation of aquatic pollutants, and enhancing photocatalytic water splitting, CO<sub>2</sub> and N<sub>2</sub> reduction, and H<sub>2</sub>O<sub>2</sub> production. Potential directions for further research in this field are outlined.</p>

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Heterogeneous Photocatalytic Transformations of Organic and Inorganic Compounds Involving Chiral Substances: A Review

  • 期刊论文

  • 发表日期：

    2025年9月1日

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  • S. Ya. Kuchmiy

摘要

The current state of research on heterogeneous systems based on chiral materials for the photocatalytic transformation of organic and inorganic substances is examined. Examples are provided illustrating methods for obtaining photoactive chiral covalent organic frameworks, coordination polymers, inorganic semiconductors, plasmonic catalysts, as well as complex systems integrating achiral photoactive components and chiral cocatalysts. Their application is demonstrated in initiating photocatalytic asymmetric synthesis of valuable organic stereoisomers, degradation of aquatic pollutants, and enhancing photocatalytic water splitting, CO2 and N2 reduction, and H2O2 production. Potential directions for further research in this field are outlined.