Scholarlink

<p>Samples of oxygen-doped crystalline carbon nitride were synthesized by a two-step ionothermal method. The obtained materials were characterized by scanning electron microscopy, X-ray diffraction, spectrophotometry, and luminescence and IR spectroscopy. has almost no effect on the morphology and crystal structure of samples, but it leads to an increase in the absorption intensity in the visible range of the spectrum and luminescence quenching. The synthesized materials exhibit high photocatalytic activity in the simultaneous production of hydrogen and benzaldehyde upon irradiation of benzyl alcohol solutions in a water/acetonitrile mixture. The apparent quantum yields of benzaldehyde and hydrogen formation under optimal conditions reach Φ ≈ 80% at λ<sub>irr</sub> = 405 nm.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Simultaneous Photocatalytic Formation of Hydrogen and Benzaldehyde in Aqueous–Acetonitrile Solutions of Benzyl Alcohol with the Participation of Crystalline Carbon Nitride Doped with Oxygen

  • 期刊论文

  • 发表日期：

    2025年1月1日

查看全文
  • G. V. Korzhak,
  • A. S. Kutsenko,
  • V. V. Shvalagin,
  • O. V. Melnichenko,
  • S. Ya. Kuchmiy

摘要

Samples of oxygen-doped crystalline carbon nitride were synthesized by a two-step ionothermal method. The obtained materials were characterized by scanning electron microscopy, X-ray diffraction, spectrophotometry, and luminescence and IR spectroscopy. has almost no effect on the morphology and crystal structure of samples, but it leads to an increase in the absorption intensity in the visible range of the spectrum and luminescence quenching. The synthesized materials exhibit high photocatalytic activity in the simultaneous production of hydrogen and benzaldehyde upon irradiation of benzyl alcohol solutions in a water/acetonitrile mixture. The apparent quantum yields of benzaldehyde and hydrogen formation under optimal conditions reach Φ ≈ 80% at λirr = 405 nm.