<p>We address basic questions concerning the atomistic-level description of “chemical” materials and their “changes” in the framework of current quantum mechanical understanding of natural phenomena. In this framework, we show how modern quantum chemical analysis of chemical reaction mechanisms, based on Fukui’s intrinsic reaction coordinate (IRC) and the Pauling-like <i>bond order</i> descriptors of natural resonance theory (NRT), can serve to resolve the logical paradoxes of Schrödinger’s cat and Wigner’s “impossibility of life” proof in common-sense manner.&#xa0;</p> Graphical Abstract <p></p>

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Chemical change: how quantum chemical resonance conceptions restore common-sense understanding of Schrödinger’s cat and Wigner’s impossible-life paradoxes

  • Frank Weinhold

摘要

We address basic questions concerning the atomistic-level description of “chemical” materials and their “changes” in the framework of current quantum mechanical understanding of natural phenomena. In this framework, we show how modern quantum chemical analysis of chemical reaction mechanisms, based on Fukui’s intrinsic reaction coordinate (IRC) and the Pauling-like bond order descriptors of natural resonance theory (NRT), can serve to resolve the logical paradoxes of Schrödinger’s cat and Wigner’s “impossibility of life” proof in common-sense manner. 

Graphical Abstract