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<p>The catalytic hydrosilylation of three different α-olefins (1-octene, 2-vinylnorbornane, and vinylferrocene) was studied using chlorodimethylsilane as an activated hydrosilane in the presence of Pt-, Rh-, and Pd-containing catalysts. The reactions can proceed with quantitative olefin conversion and high anti-Markovnikov selectivity of hydrosilane addition. Conditions for the selective anti-Markovnikov addition of chlorodimethylsilane to vinylferrocene providing more than 98% total yield were identified.</p>

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Catalytic hydrosilylation of α-olefins with chlorodimethylsilane

  • 期刊论文

  • 发表日期：

    2025年11月1日

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  • A. O. Lunin,
  • V. V. Bazhenov,
  • A. R. Egorov,
  • K. V. Zaitsev,
  • M. A. Topchiy,
  • S. A. Rzhevskiy,
  • A. F. Asachenko,
  • M. V. Bermeshev

摘要

The catalytic hydrosilylation of three different α-olefins (1-octene, 2-vinylnorbornane, and vinylferrocene) was studied using chlorodimethylsilane as an activated hydrosilane in the presence of Pt-, Rh-, and Pd-containing catalysts. The reactions can proceed with quantitative olefin conversion and high anti-Markovnikov selectivity of hydrosilane addition. Conditions for the selective anti-Markovnikov addition of chlorodimethylsilane to vinylferrocene providing more than 98% total yield were identified.