Scholarlink

<p>The racemic commercially available Grieco lactone was used as a starting material to synthesize new monocyclic precursors for the total synthesis of (±)-methylenolactocin. The key synthesis steps are the ozonolysis of the Grieco lactone derivative, preparation of regioisomeric silyl ethers, and Cu-catalyzed cross-coupling.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Discriminatory silylation of hydroxymethyl and hydroxyethyl groups in the product of the Grieco lactone conversion. Approaches to the total synthesis of (±)-methylenolactocin

  • 期刊论文

  • 发表日期：

    2025年8月1日

查看全文
  • Z. R. Makaev,
  • A. M. Gimazetdinov,
  • R. A. Sadykov

摘要

The racemic commercially available Grieco lactone was used as a starting material to synthesize new monocyclic precursors for the total synthesis of (±)-methylenolactocin. The key synthesis steps are the ozonolysis of the Grieco lactone derivative, preparation of regioisomeric silyl ethers, and Cu-catalyzed cross-coupling.