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<p>Convenient syntheses of phosphorus-substituted amines containing P(O)CH<sub>2</sub>NH and P(O)CH<sub>2</sub>NSi moieties based on the reaction between <i>N</i>,<i>N</i>′,<i>N</i>″-trisubstituted hexahydro-1,3,5-triazines and trivalent phosphorus acid esters have been developed. Various functionalization reactions (2-carboxyethylation, 2-pyridylethylation, and acylation) of the NH and NSi units of the resulting synthons proceed under mild conditions and give new functionalized phosphorus-containing amines in high yields. The resulting compounds are of interest as promising biologically active substances, water-soluble polydentate ligands, and effective extractants.</p>

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Synthesis and functionalization of P(O)CH2NH- and P(O)CH2NSi-containing amines

  • 期刊论文

  • 发表日期：

    2025年4月1日

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  • Yu. N. Bubnov,
  • A. A. Prishchenko,
  • M. V. Livantsov,
  • O. P. Novikova,
  • L. I. Livantsova,
  • S. V. Baranin

摘要

Convenient syntheses of phosphorus-substituted amines containing P(O)CH2NH and P(O)CH2NSi moieties based on the reaction between N,N′,N″-trisubstituted hexahydro-1,3,5-triazines and trivalent phosphorus acid esters have been developed. Various functionalization reactions (2-carboxyethylation, 2-pyridylethylation, and acylation) of the NH and NSi units of the resulting synthons proceed under mild conditions and give new functionalized phosphorus-containing amines in high yields. The resulting compounds are of interest as promising biologically active substances, water-soluble polydentate ligands, and effective extractants.