<p>This study quantifies morphology-dependent short-term thermal aging of soybean oil at 150&#xa0;℃ (0–96&#xa0;h) in four systems (Blank, Cu, CuO, and Cu<sub>2</sub>O) by jointly tracking gas-phase cracking signatures and liquid-phase molecular-weight evolution. The experimental campaign evaluated the time-dependent accumulation of typical dissolved gases (H<sub>2</sub>, CH<sub>4</sub>, C<sub>2</sub>H<sub>6</sub>, and C<sub>2</sub>H<sub>4</sub>), with cumulative C<sub>2</sub>H<sub>6</sub> selected as the representative cracking descriptor, and characterized liquid-phase structural growth by gel permeation chromatography using the increment of the high-molecular-weight tail area (Da &gt; 2000) relative to 0&#xa0;h as the polymerization/structural-growth descriptor. For the modeling phase, both descriptors were parameterized using a unified Hyperbolic saturation accumulation model, X(t) = at/(1 + Kt), enabling direct, morphology-to-morphology comparison of the apparent amplitude (<i>a</i>) and time-scale (<i>K</i>) parameters over the finite short-term window. The fitted parameters reveal distinct copper-morphology effects on cracking versus tail-growth behaviors, including systematic differences in cumulative levels and characteristic time scales across Blank/Cu/CuO/Cu<sub>2</sub>O. An apparent cracking–polymerization coupling coefficient (<i>η</i>) was further derived to benchmark the relative dominance of gas formation versus tail growth under each morphology. ATR-FTIR and ICP measurements provide supporting evidence for concurrent functional-group evolution and copper migration/dissolution, consistent with copper-mediated modification of the reaction network. Overall, the results establish a compact, descriptor-based apparent kinetic benchmarking scheme that enables consistent comparison of parallel cracking and structural-growth processes in soybean-oil insulating liquids under different copper morphologies.</p>

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Parallel-process characterization and apparent kinetic analysis of short-term thermal aging of soybean oil at 150 ℃ under different copper morphologies

  • Haowei Lyu,
  • Xinjie Wang,
  • Zhaojun Xu,
  • Feng Feng,
  • Chunshan Lu,
  • Qingtao Wang,
  • Jinjun Guo,
  • Qunfeng Zhang,
  • Xiaonian Li

摘要

This study quantifies morphology-dependent short-term thermal aging of soybean oil at 150 ℃ (0–96 h) in four systems (Blank, Cu, CuO, and Cu2O) by jointly tracking gas-phase cracking signatures and liquid-phase molecular-weight evolution. The experimental campaign evaluated the time-dependent accumulation of typical dissolved gases (H2, CH4, C2H6, and C2H4), with cumulative C2H6 selected as the representative cracking descriptor, and characterized liquid-phase structural growth by gel permeation chromatography using the increment of the high-molecular-weight tail area (Da > 2000) relative to 0 h as the polymerization/structural-growth descriptor. For the modeling phase, both descriptors were parameterized using a unified Hyperbolic saturation accumulation model, X(t) = at/(1 + Kt), enabling direct, morphology-to-morphology comparison of the apparent amplitude (a) and time-scale (K) parameters over the finite short-term window. The fitted parameters reveal distinct copper-morphology effects on cracking versus tail-growth behaviors, including systematic differences in cumulative levels and characteristic time scales across Blank/Cu/CuO/Cu2O. An apparent cracking–polymerization coupling coefficient (η) was further derived to benchmark the relative dominance of gas formation versus tail growth under each morphology. ATR-FTIR and ICP measurements provide supporting evidence for concurrent functional-group evolution and copper migration/dissolution, consistent with copper-mediated modification of the reaction network. Overall, the results establish a compact, descriptor-based apparent kinetic benchmarking scheme that enables consistent comparison of parallel cracking and structural-growth processes in soybean-oil insulating liquids under different copper morphologies.