Smartphone-based soil color analysis and machine learning for free iron oxide prediction in subtropical B-horizon soils
摘要
Smartphone color imaging offers a promising, field-ready alternative to laboratory or hyperspectral techniques for free iron oxide (Fed), a key control on soil carbon sequestration, nutrient buffering and site-specific agronomic decisions.
MethodsWe imaged 150 B-horizon samples from 70 soil profiles across subtropical Jiangxi, China, with five flagship smartphones (Samsung Galaxy Note 10+ 5G (SP1), Huawei Mate 30 Pro (SP2), Apple iPhone 11 (SP3), OPPO Reno3 Pro 5G (SP4), and Xiao Mi 10 Pro (SP5)) under controlled illumination, alongside a laboratory SOC710VP hyperspectral imager. The RGB data were converted to five color-space models, and hyperspectral curves were smoothed with a Savitzky-Golay filter. Support vector machine (SVM) and partial least squares regression (PLSR) models were calibrated on a Kennard-Stone algorithm (70% training, 30% validation).
ResultsIron oxides darkened soils and shifted hue towards the red-yellow domain, yielding absolute Pearson correlations up to 0.74 with saturation and hue indices. Across the independent validation set, SVM consistently surpassed PLSR; the iPhone 11-SVM combination produced the best smartphone performance (R2 = 0.64, RMSE = 5.92 g kg-1, RPD = 1.66), within 2% of the hyperspectral benchmark (R2 = 0.65). These results place the iPhone 11-SVM workflow in the “approximate quantitative” accuracy class (0.60 ≤ R2 < 0.80), suitable for variable-rate liming, micronutrient placement and carbon-budget modelling.
ConclusionFuture research should integrate robust field-calibration targets and ensemble optimisation to generalise this low-cost approach across diverse soils and illumination conditions, accelerating the adoption of smartphone-based soil diagnostics in precision agriculture.