<p>The corrosion resistance of steels containing 3–17% Cr in media with high partial pressure of CO<sub>2</sub> and varying temperature and salinity was studied. The general corrosion rate and the characteristics of local corrosion were determined gravimetrically. The structure and composition of corrosion products were analyzed using scanning electron microscopy. The results indicate that resistance to CO<sub>2</sub> corrosion increases with chromium content and that a&#xa0;Cr concentration of 3–5% is insufficient to keep the general corrosion rate below 0.1 mm/year. At temperatures above 120 °C, steels with 15–17% Cr exhibit the highest resistance to CO<sub>2</sub> corrosion. The transition of CO<sub>2</sub> to supercritical state does not significantly accelerate the corrosion of steels containing 13% Cr or more, under otherwise identical conditions.</p>

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Effect of chromium content in steel on its corrosion resistance in carbon dioxide environments

  • Igor Yu. Pyshmintsev,
  • Anna N. Maltseva,
  • Olga V. Vavilova,
  • Tatiana M. Zhuchkova,
  • Sergey I. Kotov

摘要

The corrosion resistance of steels containing 3–17% Cr in media with high partial pressure of CO2 and varying temperature and salinity was studied. The general corrosion rate and the characteristics of local corrosion were determined gravimetrically. The structure and composition of corrosion products were analyzed using scanning electron microscopy. The results indicate that resistance to CO2 corrosion increases with chromium content and that a Cr concentration of 3–5% is insufficient to keep the general corrosion rate below 0.1 mm/year. At temperatures above 120 °C, steels with 15–17% Cr exhibit the highest resistance to CO2 corrosion. The transition of CO2 to supercritical state does not significantly accelerate the corrosion of steels containing 13% Cr or more, under otherwise identical conditions.