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<p>The binary phase diagrams phenanthrene/naphthalene and phenanthrene/biphenyl at 1 atm were determined experimentally by combination of structural (XRD, TR-XRD) and thermal (DSC) analyses, to complete data points of the existing literature. While full discrimination at the solid state seems to be characterized in phenanthrene/naphthalene binary section (i.e., “usual” eutectic diagram), a total solid solution was characterized in phenanthrene/biphenyl diagram, with a drastic impact of biphenyl doping on phenanthrene solid–solid transition temperature.</p> Graphical abstract <p></p>

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Redetermination of phenanthrene–naphthalene and phenanthrene–biphenyl binary phase diagrams

  • 期刊论文

  • 发表日期：

    2026年1月7日

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  • Naylor Ahamed,
  • Loïc Lefèbvre,
  • Nicolas Couvrat

摘要

The binary phase diagrams phenanthrene/naphthalene and phenanthrene/biphenyl at 1 atm were determined experimentally by combination of structural (XRD, TR-XRD) and thermal (DSC) analyses, to complete data points of the existing literature. While full discrimination at the solid state seems to be characterized in phenanthrene/naphthalene binary section (i.e., “usual” eutectic diagram), a total solid solution was characterized in phenanthrene/biphenyl diagram, with a drastic impact of biphenyl doping on phenanthrene solid–solid transition temperature.

Graphical abstract