<p>The evaporation behaviour of tellurium from liquid lead–bismuth eutectic was investigated using the transpiration method in an inert atmosphere between 220 and 600&#xa0;°C. The results showed a significant retention of Te within the LBE matrix compared to the vapour pressure of pure Te. The temperature dependence of the Henry’s law volatility constant above 350&#xa0;°C was determined using data from this study and compared with data reported in the literature. A noticeable deviation from linearity was observed at temperatures below 350&#xa0;°C, possibly due to surface enrichment phenomena connected to chemical reactions enhancing Te volatilisation, highlighting the need for further investigation at lower temperatures.</p>

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Evaporation of tellurium from liquid lead–bismuth eutectic studied by the transpiration method

  • Ana Ivan,
  • Vladislav Zobnin,
  • Robert Eichler,
  • Alexander Vögele,
  • Dominik Herrmann,
  • Rugard Dressler,
  • Jörg Neuhausen

摘要

The evaporation behaviour of tellurium from liquid lead–bismuth eutectic was investigated using the transpiration method in an inert atmosphere between 220 and 600 °C. The results showed a significant retention of Te within the LBE matrix compared to the vapour pressure of pure Te. The temperature dependence of the Henry’s law volatility constant above 350 °C was determined using data from this study and compared with data reported in the literature. A noticeable deviation from linearity was observed at temperatures below 350 °C, possibly due to surface enrichment phenomena connected to chemical reactions enhancing Te volatilisation, highlighting the need for further investigation at lower temperatures.