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<p>Ammonium ferric hexacyanoferrate is a veterinary-medical milestone and antidote against radiocesium, well-known as <i>Giese-salt</i> after the Chernobyl disaster fed to domestic and wild animals, which shows even a rich interplay of properties in nanostructural chemistry and ferromagnetism. Among the broad analytical techniques, the ambivalence of macroscopic micrometer-sized agglomerates and nanoparticle sizes, a suggested enlarged <InlineEquation ID="IEq1"> <EquationSource Format="TEX">\(\text {Fe}^{\textrm{II}}{-}\text {C}\equiv \text {N}{-}\text {Fe}^{\textrm{III}}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <msup> <mtext>Fe</mtext> <mtext>II</mtext> </msup> <mo>-</mo> <mtext>C</mtext> <mo>≡</mo> <mtext>N</mtext> <mo>-</mo> <msup> <mtext>Fe</mtext> <mtext>III</mtext> </msup> </mrow> </math></EquationSource> </InlineEquation> bond length by Fe K-edge XAFS results and multi-level spin relaxation in <InlineEquation ID="IEq2"> <EquationSource Format="TEX">\(^{57}\)</EquationSource> <EquationSource Format="MATHML"><math> <mmultiscripts> <mrow /> <mrow /> <mn>57</mn> </mmultiscripts> </math></EquationSource> </InlineEquation>Fe Mössbauer spectroscopy are highlighted. This sets this underestimated compound in a new light, e.g., for modern biomedicine and biofunctionality, extending its essential importance in addition to hypothetical future nuclear incidents.</p>

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Fine and hyperfine interactions with multi-level spin relaxation of the purified Giese-salt in veterinary medicine: Prussian blue compound ammonium-ferric-hexacyano-ferrate

  • 期刊论文

  • 出版模式：

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  • 发表日期：

    2026年4月2日

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  • Sascha A. Bräuninger,
  • Damian A. Motz,
  • Sebastian Praetz,
  • Felix Seewald,
  • Katharina Strecker,
  • Carla Vogt,
  • Hans-Henning Klauss,
  • Birgit Kanngießer,
  • Hermann Seifert

摘要

Ammonium ferric hexacyanoferrate is a veterinary-medical milestone and antidote against radiocesium, well-known as Giese-salt after the Chernobyl disaster fed to domestic and wild animals, which shows even a rich interplay of properties in nanostructural chemistry and ferromagnetism. Among the broad analytical techniques, the ambivalence of macroscopic micrometer-sized agglomerates and nanoparticle sizes, a suggested enlarged \(\text {Fe}^{\textrm{II}}{-}\text {C}\equiv \text {N}{-}\text {Fe}^{\textrm{III}}\) Fe II - C ≡ N - Fe III bond length by Fe K-edge XAFS results and multi-level spin relaxation in \(^{57}\) 57 Fe Mössbauer spectroscopy are highlighted. This sets this underestimated compound in a new light, e.g., for modern biomedicine and biofunctionality, extending its essential importance in addition to hypothetical future nuclear incidents.