Study of structure deterioration of medical thermoplastic polyurethane (TPU) after irradiation by electron beam
摘要
Thermoplastic polyurethane (TPU) is widely used in medical applications because of its biocompatibility, flexibility, and durability. The TPU instruments and equipment are subjected to sterilization procedures before being utilized in medical uses. In this research, the TPU was irradiated by an electron beam (EB) at different doses of 20, 30, 50, 100, and 200 kGy. After irradiation, we tracked the formed free radical concentrations using Electron Spin Resonance (ESR), monitoring the intermolecular change of the TPU material. This tracking of the FRC is detected at different time intervals, including 0 days, 1 day, 3 days, 7 days, 10 days, 20 days, 30 days, and 50 days. Moreover, the impact of the EB on the intramolecular change of TPU was checked by additional techniques such as FTIR, XRD, SEM, and TGA. Moreover, the physical properties of TPU were assessed, including tensile strength and elongation@break. Furthermore, the modulus of elasticity (ME) is calculated at different strain percentages (100%, 300%, and 500%). As a result of this research, the TPU has good properties against EB irradiation within the sterilization doses (20–50 kGy).