Development and performance evaluation of composite material prepared from recycled polyethylene terephthalate (PET) and perlite
摘要
This study explores the reuse of post-consumer polyethylene terephthalate (PET) bottles through the development of recycled PET (RPET)/perlite composites exhibiting enhanced mechanical stiffness and thermal insulation properties. Untreated and alkaline-treated perlite were incorporated into the RPET matrix at filler loadings of 0–20 wt% using solid-state blending followed by hot compression molding. Structural, morphological, thermal, and mechanical properties were evaluated using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), thermal conductivity measurements, dynamic modulus obtained through vibration analysis, and bending rigidity and strength through a three-point bending test. The incorporation of perlite reduced the thermal conductivity of RPET from 0.159 W·m⁻¹·K⁻¹ to 0.10 W·m⁻¹·K⁻¹ at 20 wt% filler loading. Mechanical testing showed a progressive increase in flexural modulus with filler content, reaching approximately 4.5 GPa for the composite containing 20 wt% alkaline-treated perlite, exceeding both neat RPET and composites prepared with untreated perlite. XRD analysis indicated a decrease in RPET crystallinity with increasing filler content, while TGA revealed a slight increase in thermal stability (Tonset) in filled systems. The results demonstrate that surface-modified perlite can improve the stiffness and insulation performance of RPET composites, highlighting their potential for lightweight structural and insulating applications.