Direct ink writing of styrene-ethylene-propylene-styrene block copolymer: ink formulation, printability and physicomechanical properties
摘要
This study explores direct ink writing (DIW) based additive manufacturing of a commercially available styrene-ethylene-propylene-styrene (SEPS) block copolymer. To formulate suitable inks used as the feedstock materials for DIW, the interaction of ten distinct solvents with the constituent blocks of the SEPS block copolymer was studied theoretically using Hansen solubility parameter (HSP) analysis, which identified toluene as the most appropriate solvent. The printability of the developed ink was assessed through viscosity measurements, thixotropy analysis and evaluation of shape stability of the extrudate inks. These studies suggested that inks containing 35–40 wt% SEPS exhibited adequate printability and shape stability. The mechanical, physical, morphological properties and defects in the printed samples were also investigated. The printed samples experienced comparatively high shrinkage (~ 26–52%) in thickness direction owing to solvent evaporation. Field emission scanning electron microscopy (FESEM) images revealed good inter- and intra-layer coalescence behaviour. However, pore-like defects were observed in the printed samples and their size and number were found to be strongly dependent on the solvent content in the ink. Samples printed with 35–40 wt% inks demonstrated high elongation at break (~ 900–1000%), tensile strength of 6.1–7.2 MPa, and Shore A hardness values of ~ 62–63.