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<p>Anthranilic acid (2-amino benzoic acid), a medicinally important compound, is derived from indigo dye (extracted from <i>Indigofera tinctoria</i>) exhibits potential to form complexes with transition metals. We have used sodium salt of anthranilic acid as anion to prepare a new, C<sub>2</sub>-symmetrical, third-generation, hydrophobic task-specific Ionic Liquid (IL); dioctylimidazolium anthranilate [DOIM][AN] and successfully investigated its ability to selectively extract Co<sup>2+</sup> and/or Ni<sup>2+</sup> from their aqueous solutions. Co<sup>2+</sup> and Ni<sup>2+</sup>, both exhibit similar physical and chemical properties. The IL showed good efficiency in the separation of Co<sup>2+</sup> and Ni<sup>2+</sup> from their aqueous solutions within five minutes at room temperature. The IL was recycled under basic conditions and reused. The extraction efficiencies were determined through Atomic Absorption Spectroscopy (AAS). The characterization of IL was done through Electron Spray Ionization Mass spectroscopy (ESI–MS), Nuclear Magnetic Resonance (NMR), and Infrared spectroscopic (IR) techniques. The rheometric analysis revealed that IL has Newtonian-type behavior.</p>

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Anthranilic Acid Based Imidazolium Ionic Liquids: Design, Synthesis, Characterization, and Application in Co2+ and Ni2+ Separation from Mixture

  • 期刊论文

  • 发表日期：

    2025年3月24日

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  • Komal Aziz Gill,
  • Shoaib Muhammad,
  • Kashif Riaz,
  • Imran Ali Hashmi,
  • Muhammad Naveed Javed,
  • Agha Arslan Wasim,
  • William Henderson,
  • Ahmed Bari,
  • Firdous Imran Ali

摘要

Anthranilic acid (2-amino benzoic acid), a medicinally important compound, is derived from indigo dye (extracted from Indigofera tinctoria) exhibits potential to form complexes with transition metals. We have used sodium salt of anthranilic acid as anion to prepare a new, C2-symmetrical, third-generation, hydrophobic task-specific Ionic Liquid (IL); dioctylimidazolium anthranilate [DOIM][AN] and successfully investigated its ability to selectively extract Co2+ and/or Ni2+ from their aqueous solutions. Co2+ and Ni2+, both exhibit similar physical and chemical properties. The IL showed good efficiency in the separation of Co2+ and Ni2+ from their aqueous solutions within five minutes at room temperature. The IL was recycled under basic conditions and reused. The extraction efficiencies were determined through Atomic Absorption Spectroscopy (AAS). The characterization of IL was done through Electron Spray Ionization Mass spectroscopy (ESI–MS), Nuclear Magnetic Resonance (NMR), and Infrared spectroscopic (IR) techniques. The rheometric analysis revealed that IL has Newtonian-type behavior.