<p>The study of multiple <i>n</i>-CuO<InlineEquation ID="IEq9"> <EquationSource Format="TEX">\(_{2}\)</EquationSource> </InlineEquation>-layer (multilayer) cuprate high-temperature superconductors in the singlet-bond (SB) superconductivity theory reveals that the large enhancements of superconducting transition temperatures <InlineEquation ID="IEq10"> <EquationSource Format="TEX">\(T^{(n)}_{c}\)</EquationSource> </InlineEquation> are the result of increased condensation energy which is added to the layer by the motion of interlayer-tunneled condensed SB-pairs from the adjacent layers. This mechanism is endorsed by the experimental observations of the large enhancements of muon-spin-relaxation rate <InlineEquation ID="IEq11"> <EquationSource Format="TEX">\(\sigma ^{(n)}(0)\)</EquationSource> </InlineEquation> proportional to inverse squared London penetration depth at <InlineEquation ID="IEq12"> <EquationSource Format="TEX">\(T = 0\)</EquationSource> </InlineEquation>, <InlineEquation ID="IEq13"> <EquationSource Format="TEX">\(\sigma ^{(n)}(0) \propto 1/\lambda ^{(n)}(0)^{2}\)</EquationSource> </InlineEquation>, where <InlineEquation ID="IEq14"> <EquationSource Format="TEX">\(2 |\Psi ^{(n)}|^{2}\)</EquationSource> </InlineEquation> in <InlineEquation ID="IEq15"> <EquationSource Format="TEX">\(1/\lambda ^{(n)}(0)^{2} = 4 \pi 2 |\Psi ^{(n)}|^{2} e^{2}/mc^{2}\)</EquationSource> </InlineEquation> (<InlineEquation ID="IEq16"> <EquationSource Format="TEX">\(\Psi ^{(n)}\)</EquationSource> </InlineEquation> the order-parameter of Ginzburg-Landau free energy) is enhanced by the same factor as the condensation energy increase due to the kinetic energy increase. These enhancements are a very unique effect particular to multilayer superconductors where while SB-pairs in the normal-state pseudogap insulator phase are strictly two-dimensional and confined to one CuO<InlineEquation ID="IEq17"> <EquationSource Format="TEX">\(_{2}\)</EquationSource> </InlineEquation>-layer, SB-pairs in the superconductng phase can tunnel to adjacent layers where they increase both condensation and kinetic energies through the coherent motion. The calculations of <InlineEquation ID="IEq18"> <EquationSource Format="TEX">\(T^{(n)}_{c}\)</EquationSource> </InlineEquation> and <InlineEquation ID="IEq19"> <EquationSource Format="TEX">\(1/\lambda ^{(n)}(0)^{2}\)</EquationSource> </InlineEquation> give the results; (1) <InlineEquation ID="IEq20"> <EquationSource Format="TEX">\(T^{(n)}_{c}\)</EquationSource> </InlineEquation> and <InlineEquation ID="IEq21"> <EquationSource Format="TEX">\(1/\lambda ^{(n)}(0)^{2}\)</EquationSource> </InlineEquation> increase from <InlineEquation ID="IEq22"> <EquationSource Format="TEX">\(n = 1\)</EquationSource> </InlineEquation> to <InlineEquation ID="IEq23"> <EquationSource Format="TEX">\(n = 3\)</EquationSource> </InlineEquation>, decrease from <InlineEquation ID="IEq24"> <EquationSource Format="TEX">\(n = 3\)</EquationSource> </InlineEquation> to <InlineEquation ID="IEq25"> <EquationSource Format="TEX">\(n = 5\)</EquationSource> </InlineEquation> and then level off for <InlineEquation ID="IEq26"> <EquationSource Format="TEX">\(n \ge 6\)</EquationSource> </InlineEquation>, having the maxima <InlineEquation ID="IEq27"> <EquationSource Format="TEX">\(T^{(3)}_{c}\)</EquationSource> </InlineEquation> and <InlineEquation ID="IEq28"> <EquationSource Format="TEX">\(1/\lambda ^{(3)}(0)^{2}\)</EquationSource> </InlineEquation> always at <InlineEquation ID="IEq29"> <EquationSource Format="TEX">\(n = 3\)</EquationSource> </InlineEquation>, (2) the maximum superconducting transition temperature <InlineEquation ID="IEq30"> <EquationSource Format="TEX">\(T^{max}_{c}\)</EquationSource> </InlineEquation> that can be achieved at the ambient pressure by <InlineEquation ID="IEq31"> <EquationSource Format="TEX">\(T^{(3)}_{c}\)</EquationSource> </InlineEquation> in any multilayer cuprates is bounded by the maximum condensation onset-temperature <InlineEquation ID="IEq32"> <EquationSource Format="TEX">\(T_{0}^{max} \sim 156 K\)</EquationSource> </InlineEquation> at the optimal doping <InlineEquation ID="IEq33"> <EquationSource Format="TEX">\(\delta _{m} \sim 0.15\)</EquationSource> </InlineEquation>, (3) the multilayer enhancements <InlineEquation ID="IEq34"> <EquationSource Format="TEX">\(T^{(n)}_{c} / T^{(1)}_{c}\)</EquationSource> </InlineEquation> as a function of <i>n</i> of all the multilayer cuprate superconductors examined are the same and can be expressed by a singe curve (except with one correction to the low <InlineEquation ID="IEq35"> <EquationSource Format="TEX">\(T^{(1)}_{c}\)</EquationSource> </InlineEquation> values as explained in the text). This <InlineEquation ID="IEq36"> <EquationSource Format="TEX">\(T^{(n)}_{c} / T^{(1)}_{c}\)</EquationSource> </InlineEquation> - <i>n</i> curve is well reproduced by the multilayer SB superconductivity with the restricted entropy (RE) imposed on the pseudogap insulator phase.</p>

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Singlet-bond Superconductivity Theory for the Simultaneous Enhancements of \(T^{(n)}_{c}\) and \(\sigma ^{(n)}(0) \propto 1/\lambda ^{(n)}(0)^{2}\) in Multiple n-CuO\(_{2}\)-layer Cuprate High-\(T_{c}\) Superconductors

  • Hiroyuki Kaga

摘要

The study of multiple n-CuO \(_{2}\) -layer (multilayer) cuprate high-temperature superconductors in the singlet-bond (SB) superconductivity theory reveals that the large enhancements of superconducting transition temperatures \(T^{(n)}_{c}\) are the result of increased condensation energy which is added to the layer by the motion of interlayer-tunneled condensed SB-pairs from the adjacent layers. This mechanism is endorsed by the experimental observations of the large enhancements of muon-spin-relaxation rate \(\sigma ^{(n)}(0)\) proportional to inverse squared London penetration depth at \(T = 0\) , \(\sigma ^{(n)}(0) \propto 1/\lambda ^{(n)}(0)^{2}\) , where \(2 |\Psi ^{(n)}|^{2}\) in \(1/\lambda ^{(n)}(0)^{2} = 4 \pi 2 |\Psi ^{(n)}|^{2} e^{2}/mc^{2}\) ( \(\Psi ^{(n)}\) the order-parameter of Ginzburg-Landau free energy) is enhanced by the same factor as the condensation energy increase due to the kinetic energy increase. These enhancements are a very unique effect particular to multilayer superconductors where while SB-pairs in the normal-state pseudogap insulator phase are strictly two-dimensional and confined to one CuO \(_{2}\) -layer, SB-pairs in the superconductng phase can tunnel to adjacent layers where they increase both condensation and kinetic energies through the coherent motion. The calculations of \(T^{(n)}_{c}\) and \(1/\lambda ^{(n)}(0)^{2}\) give the results; (1) \(T^{(n)}_{c}\) and \(1/\lambda ^{(n)}(0)^{2}\) increase from \(n = 1\) to \(n = 3\) , decrease from \(n = 3\) to \(n = 5\) and then level off for \(n \ge 6\) , having the maxima \(T^{(3)}_{c}\) and \(1/\lambda ^{(3)}(0)^{2}\) always at \(n = 3\) , (2) the maximum superconducting transition temperature \(T^{max}_{c}\) that can be achieved at the ambient pressure by \(T^{(3)}_{c}\) in any multilayer cuprates is bounded by the maximum condensation onset-temperature \(T_{0}^{max} \sim 156 K\) at the optimal doping \(\delta _{m} \sim 0.15\) , (3) the multilayer enhancements \(T^{(n)}_{c} / T^{(1)}_{c}\) as a function of n of all the multilayer cuprate superconductors examined are the same and can be expressed by a singe curve (except with one correction to the low \(T^{(1)}_{c}\) values as explained in the text). This \(T^{(n)}_{c} / T^{(1)}_{c}\) - n curve is well reproduced by the multilayer SB superconductivity with the restricted entropy (RE) imposed on the pseudogap insulator phase.