<p>In this work, we investigated the critical behavior and magnetocaloric effect of Pr<sub>0.55</sub>Sr<sub>0.45-x</sub>Na<sub>x</sub>MnO<sub>3</sub> manganites (x = 0, 0.05 and 0.1) by using critical exponent analysis and Landau theory. The study revealed that the mean-field, 3D-Heisenberg and 3D-XY models are the best for describing the magnetic interactions for x = 0, 0.05 and 0.1 samples, respectively. With increasing sodium content, the magnetic interactions display a striking change from long-range to short-range interactions, which may be ascribed to an increase in Mn<sup>4+</sup> ions concentration and magnetocrystalline anisotropy. Using Landau theory, we have confirmed that the magnetic transition around T<sub>C</sub> is of second-order. An agreement was found between the magnetic entropy change values estimated by Landau theory and those obtained using Maxwell relation for a magnetic field equal to 2 T. This confirms the validity of Landau theory to estimate the magnetocaloric effect of Pr<sub>0.55</sub>Sr<sub>0.45-x</sub>Na<sub>x</sub>MnO<sub>3</sub> samples. The small deviation obtained for our samples below T<sub>C</sub> can be attributed to the existence of magnetic disorder in the ferromagnetic phase.</p>

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Critical Behavior and Landau Theory in Pr0.55Sr0.45-xNaxMnO3 Manganites

  • W. Mabrouki,
  • A. Krichene,
  • W. Boujelben

摘要

In this work, we investigated the critical behavior and magnetocaloric effect of Pr0.55Sr0.45-xNaxMnO3 manganites (x = 0, 0.05 and 0.1) by using critical exponent analysis and Landau theory. The study revealed that the mean-field, 3D-Heisenberg and 3D-XY models are the best for describing the magnetic interactions for x = 0, 0.05 and 0.1 samples, respectively. With increasing sodium content, the magnetic interactions display a striking change from long-range to short-range interactions, which may be ascribed to an increase in Mn4+ ions concentration and magnetocrystalline anisotropy. Using Landau theory, we have confirmed that the magnetic transition around TC is of second-order. An agreement was found between the magnetic entropy change values estimated by Landau theory and those obtained using Maxwell relation for a magnetic field equal to 2 T. This confirms the validity of Landau theory to estimate the magnetocaloric effect of Pr0.55Sr0.45-xNaxMnO3 samples. The small deviation obtained for our samples below TC can be attributed to the existence of magnetic disorder in the ferromagnetic phase.