<p>We investigated the magnetic, magnetocaloric, and hysteresis characteristics of the antiperovskite material Fe<InlineEquation ID="IEq1"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="10948_2025_6957_Article_IEq1.gif" Format="GIF" Height="10" Rendition="HTML" Resolution="72" Type="Linedraw" Width="8" /> </InlineMediaObject> <EquationSource Format="TEX">\(_{3}\)</EquationSource> <EquationSource Format="MATHML"><math> <mmultiscripts> <mrow /> <mn>3</mn> <mrow /> </mmultiscripts> </math></EquationSource> </InlineEquation>ZnN by employing the mean-field approximation method. The findings indicate that magnetization gradually declines with rising temperature, whereas the application of an external magnetic field elevates the critical temperature <InlineEquation ID="IEq2"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="10948_2025_6957_Article_IEq2.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="18" /> </InlineMediaObject> <EquationSource Format="TEX">\(T_{c}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mi>T</mi> <mi>c</mi> </msub> </math></EquationSource> </InlineEquation> by promoting greater alignment of the magnetic moments. A peak in the magnetic entropy change <InlineEquation ID="IEq3"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="10948_2025_6957_Article_IEq3.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="51" /> </InlineMediaObject> <EquationSource Format="TEX">\(-\Delta S_{m}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mo>-</mo> <mi mathvariant="normal">Δ</mi> <msub> <mi>S</mi> <mi>m</mi> </msub> </mrow> </math></EquationSource> </InlineEquation>, at <InlineEquation ID="IEq4"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="10948_2025_6957_Article_IEq4.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="18" /> </InlineMediaObject> <EquationSource Format="TEX">\(T_{c}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mi>T</mi> <mi>c</mi> </msub> </math></EquationSource> </InlineEquation>, indicating a significant magnetocaloric effect, ideal for magnetic refrigeration applications. Additionally, the relative cooling power (RCP) exhibits a linear increase with the strength of the magnetic field. The hysteresis analysis reveals a gradual decrease in coercivity and remanence with rising temperature, ultimately leading to the disappearance of the hysteresis loop above <InlineEquation ID="IEq5"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="10948_2025_6957_Article_IEq5.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="18" /> </InlineMediaObject> <EquationSource Format="TEX">\(T_{c}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mi>T</mi> <mi>c</mi> </msub> </math></EquationSource> </InlineEquation>, signaling a transition to the paramagnetic phase. These findings suggest that the Fe<InlineEquation ID="IEq6"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="10948_2025_6957_Article_IEq6.gif" Format="GIF" Height="10" Rendition="HTML" Resolution="72" Type="Linedraw" Width="8" /> </InlineMediaObject> <EquationSource Format="TEX">\(_{3}\)</EquationSource> <EquationSource Format="MATHML"><math> <mmultiscripts> <mrow /> <mn>3</mn> <mrow /> </mmultiscripts> </math></EquationSource> </InlineEquation>ZnN compound holds promise as a candidate material for magnetic refrigeration applications.</p>

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Mean-Field Study of Magnetic Properties and Magnetocaloric Effect in Iron(III) Nitride-Based Antiperovskite Materials

  • M. Salama,
  • H. Kerrai,
  • H. Saadi,
  • E. M. Jalal,
  • N. Hachem,
  • E. B. Choubabi,
  • M. El Bouziani

摘要

We investigated the magnetic, magnetocaloric, and hysteresis characteristics of the antiperovskite material Fe \(_{3}\) 3 ZnN by employing the mean-field approximation method. The findings indicate that magnetization gradually declines with rising temperature, whereas the application of an external magnetic field elevates the critical temperature \(T_{c}\) T c by promoting greater alignment of the magnetic moments. A peak in the magnetic entropy change \(-\Delta S_{m}\) - Δ S m , at \(T_{c}\) T c , indicating a significant magnetocaloric effect, ideal for magnetic refrigeration applications. Additionally, the relative cooling power (RCP) exhibits a linear increase with the strength of the magnetic field. The hysteresis analysis reveals a gradual decrease in coercivity and remanence with rising temperature, ultimately leading to the disappearance of the hysteresis loop above \(T_{c}\) T c , signaling a transition to the paramagnetic phase. These findings suggest that the Fe \(_{3}\) 3 ZnN compound holds promise as a candidate material for magnetic refrigeration applications.