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<p>Aflatoxin B<sub>1</sub> (AFB<sub>1</sub>) is a potent carcinogen which threatens human health, therefore, rapid and efficient detection of AFB<sub>1</sub> is highly needed. Herein, a novel turn-on ratiometric fluorescent nanoprobe (RhB@NH<sub>2</sub>-MIL-53(Al)) was fabricated via a facial grinding for sensing AFB<sub>1</sub>. With increasing AFB<sub>1</sub> concentration, the fluorescence of Al-MOFs was enhanced due to molecular clamp action and electron transport, while the fluorescence of RhB remained almost unchanged, thus obtaining limit of detection (LOD) of 4.16 nM in the range of 0.005–2.56 µM. The sensor demonstrated excellent anti-interference capabilities and gave reasonable results when used to measure AFB<sub>1</sub> in grains. In addition, a paper-based portable sensor for AFB<sub>1</sub> detection was developed with a LOD of 29.89 nM in the range of 0.04–12.8 µM, while the colour changes from light pink to blue upon UV light exposure, making it a straightforward and effective technique for the on-site determination of AFB<sub>1</sub>.</p> Graphical Abstract <p></p>

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A Turn-On Ratiometric Fluorescence Probe Based on Dye@MOFs for Visual Detection of AFB1 with Paper Sensor Assisted by Smartphone

  • 期刊论文

  • 发表日期：

    2025年2月10日

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  • Zhangmin Li,
  • Zuopeng Li,
  • Qianyi Li,
  • Min Wang,
  • Chang-qing Miao,
  • Yajia Liu,
  • Sanbing Zhang

摘要

Aflatoxin B1 (AFB1) is a potent carcinogen which threatens human health, therefore, rapid and efficient detection of AFB1 is highly needed. Herein, a novel turn-on ratiometric fluorescent nanoprobe (RhB@NH2-MIL-53(Al)) was fabricated via a facial grinding for sensing AFB1. With increasing AFB1 concentration, the fluorescence of Al-MOFs was enhanced due to molecular clamp action and electron transport, while the fluorescence of RhB remained almost unchanged, thus obtaining limit of detection (LOD) of 4.16 nM in the range of 0.005–2.56 µM. The sensor demonstrated excellent anti-interference capabilities and gave reasonable results when used to measure AFB1 in grains. In addition, a paper-based portable sensor for AFB1 detection was developed with a LOD of 29.89 nM in the range of 0.04–12.8 µM, while the colour changes from light pink to blue upon UV light exposure, making it a straightforward and effective technique for the on-site determination of AFB1.

Graphical Abstract