Scholarlink

<p>Cellulose–polyaniline (CP) composites were synthesized via ultrasonic-assisted in-situ oxidative polymerization using cellulose microfibers derived from waste paper. The influence of cellulose loading (5–15 wt%) on structural, morphological, and electrochemical properties was systematically investigated. Spectroscopic and diffraction analyses confirmed hydrogen bonding interactions between cellulose and polyaniline, promoting improved interfacial compatibility. FESEM analysis revealed that 10 wt% cellulose resulted in uniform dispersion, while higher loading induced agglomeration. The optimized composite (10CP) exhibited significantly enhanced electrical conductivity (2.45 × 10<sup>3</sup> S cm⁻<sup>1</sup>) and reduced charge transfer resistance compared to pristine PANI. Electrochemical measurements demonstrated improved redox activity and capacitive behavior, attributed to synergistic interactions and efficient charge transport pathways. This study highlights the potential of waste-derived cellulose as a sustainable reinforcing filler for high-performance conductive composites in electronic and energy storage applications.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Ultrasonic-assisted in-situ synthesis of waste-derived cellulose–polyaniline composites with enhanced electrical conductivity and electrochemical performance

  • 期刊论文

  • 发表日期：

    2026年7月14日

查看全文
  • Anis Farhana Abdul Rahman,
  • Agus Arsad,
  • Nor Eman Ismail,
  • Siti Rahmah Suradi,
  • Muslim Abdurrahman,
  • Mohammed A. Samba

摘要

Cellulose–polyaniline (CP) composites were synthesized via ultrasonic-assisted in-situ oxidative polymerization using cellulose microfibers derived from waste paper. The influence of cellulose loading (5–15 wt%) on structural, morphological, and electrochemical properties was systematically investigated. Spectroscopic and diffraction analyses confirmed hydrogen bonding interactions between cellulose and polyaniline, promoting improved interfacial compatibility. FESEM analysis revealed that 10 wt% cellulose resulted in uniform dispersion, while higher loading induced agglomeration. The optimized composite (10CP) exhibited significantly enhanced electrical conductivity (2.45 × 103 S cm⁻1) and reduced charge transfer resistance compared to pristine PANI. Electrochemical measurements demonstrated improved redox activity and capacitive behavior, attributed to synergistic interactions and efficient charge transport pathways. This study highlights the potential of waste-derived cellulose as a sustainable reinforcing filler for high-performance conductive composites in electronic and energy storage applications.